([2-(N,N-dimethylamino)ethyl]cyclopentadienyl(phthalimidato))nickel(II) | 916461-36-4

• 英文名称: ([2-(N,N-dimethylamino)ethyl]cyclopentadienyl(phthalimidato))nickel(II)
• CAS: 916461-36-4
• 化学式: C₁₇H₁₈N₂NiO₂
• 分子量: 341.032
• InChiKey: MPCMWNLTEGNVPB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ([2-(N,N-dimethylamino)ethyl]cyclopentadienyl(phthalimidato))nickel(II) 、 甲苯 以 甲苯 为溶剂， 生成 ([2-(N,N-dimethylamino)ethyl]cyclopentadienyl(phthalimidato))nickel(II)*0.5toluene
  参考文献：
  名称：

  Novel complexes of nickel with N-heterocyclic ligands and the hemilabile [2-(dimethylamino)ethyl]cyclopentadienyl group

  摘要：

  Starting out from [(CpNiI)-Ni-N] (1), three new derivatives with polar sigma(Ni-N) bonds of the type [(CPNiL)-Ni-N] (Cp-N = [2-(N,N-dimethylamino)eth-1-yl]cyclopentadienyl; L = carbazolato, 3; maleimidato, 4; phthalimidato, 5) were synthesized by salt elimination. The new compounds were characterized by H-1 and C-13{H-1} NMR spectroscopy, elemental analysis, mass spectrometry and, in the case of 3 and 5, by single crystal X-ray diffraction studies. The presence of electron withdrawing groups R at the negatively polarized N-atom, allowing for charge delocalization strongly contribute to the stability of amido and/or imidato complexes at the (CpNi)-Ni-N fragment. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.016
• 作为产物：
  描述：

  邻苯二甲酸亚胺 、 (η(5):η(1)-[2-(dimethylamino)ethyl]cyclopentadienyl)iodonickel(II) 在 diethylamine 作用下， 以 二乙胺 为溶剂， 以81%的产率得到([2-(N,N-dimethylamino)ethyl]cyclopentadienyl(phthalimidato))nickel(II)
  参考文献：
  名称：

  Novel complexes of nickel with N-heterocyclic ligands and the hemilabile [2-(dimethylamino)ethyl]cyclopentadienyl group

  摘要：

  Starting out from [(CpNiI)-Ni-N] (1), three new derivatives with polar sigma(Ni-N) bonds of the type [(CPNiL)-Ni-N] (Cp-N = [2-(N,N-dimethylamino)eth-1-yl]cyclopentadienyl; L = carbazolato, 3; maleimidato, 4; phthalimidato, 5) were synthesized by salt elimination. The new compounds were characterized by H-1 and C-13{H-1} NMR spectroscopy, elemental analysis, mass spectrometry and, in the case of 3 and 5, by single crystal X-ray diffraction studies. The presence of electron withdrawing groups R at the negatively polarized N-atom, allowing for charge delocalization strongly contribute to the stability of amido and/or imidato complexes at the (CpNi)-Ni-N fragment. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.016