| 1443750-75-1

• CAS: 1443750-75-1
• 化学式: C₂₆H₃₃Cl₂NiP₃
• 分子量: 568.065
• InChiKey: NEIDLSQIDQRVDM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 phenyl-bis(2-diethylphosphinophenyl)-phosphine 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Improved synthesis of a trisphosphine ligand and crystallographic characterization of the ligand and nickel thiocyanate complex

  摘要：

  Improved syntheses of o-C6H4(PEt2)(X) (X = F, Br, I) and the trisphosphine PhP[o-C6H4(PEt2)](2) have been developed and are applicable to a wide variety of phosphine substituents. The trisphosphine, PhP(o-Ph-PEt2)(2), has been fully characterized spectroscopically and, for the first time, crystallographically. Reaction of the P3 ligand with one equivalent of NiCl2 or Ni(BF4)(2) followed by 2.5 equivalents of KNCS produces the monometallic complexes Ni(X)(2)[kappa(3)-PhP(o-Ph-PEt2)(2)], (X = Cl or NCS). The nickel thiocyanate complex has been characterized via a crystal structure. The nickel center has a square pyramidal structure with one of the NCS ligands occupying the apical coordination site. The Ni complex crystallizes in the P (1) over bar space group with an unusual six molecules in the asymmetric unit (Z' = 6), and twelve in the unit cell. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.028