[(p-Me-C6H4NCH2CH2)2N2C3H2]Zr(trimethylsilylmethyl)2 | 728949-08-4

• 英文名称: [(p-Me-C6H4NCH2CH2)2N2C3H2]Zr(trimethylsilylmethyl)2
• CAS: 728949-08-4
• 化学式: C₂₉H₄₆N₄Si₂Zr
• 分子量: 598.106
• InChiKey: FBYXQGLFLIDULJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N'-((1H-imidazole-1,3(2H)-diyl)bis(ethane-2,1-diyl))bis(4-methylaniline) 、 tetrakis(trimethylsilylmethyl)zirconium(IV) 以 not given 为溶剂， 生成 [(p-Me-C6H4NCH2CH2)2N2C3H2]Zr(trimethylsilylmethyl)2
  参考文献：
  名称：

  Tridentate Amido Carbene Ligands in Early-Transition-Metal Coordination Chemistry

  摘要：

  Coordination of the new tridentate N-heterocyclic carbene ligand precursor (p-Me-C6H4NHCH2-CH2)(2)N2C3H2 to Zr(IV) generates an [NCN] donor set where the N represents an amido unit and the C corresponds to the N-heterocyclic carbene. This ancillary ligand allows for the isolation and structural characterization of zirconium amido, chloro, and alkyl derivatives; the carbene donor is rendered stable to dissociation because of its central disposition between two anionic amido units.

  DOI：

  10.1021/om0498089