[Ru3O(C2H3O2)6(4-picoline)2CH3OH]PF6 | 861238-81-5

• 英文名称: [Ru3O(C2H3O2)6(4-picoline)2CH3OH]PF6
• 英文别名: μ-oxo-hexaacetate-bis(4-methylpyridine)triruthenium methanol hexafluorophosphate；[Ru₃O(C₂H₃O₂)₆(4-picoline)₂CH₃OH]PF₆；[Ru₃O(C₂H₃O₂)₆(pic)₂CH₃OH]PF₆；[Ru3O(Ac)6(pic)2(CH3OH)]PF6
• CAS: 861238-81-5
• 化学式: C₂₅H₃₆N₂O₁₄Ru₃*F₆P
• 分子量: 1036.74
• InChiKey: VLOCLFUUDCZZLX-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Ru3O(C2H3O2)6(4-picoline)2CH3OH]PF6 、 氧化亚氮 以 二氯甲烷 为溶剂， 以72%的产率得到μ-oxo-hexaacetate-bis(4-methylpyridine)triruthenium nitrosyl hexafluorophosphate
  参考文献：
  名称：

  A nitric oxide releaser based on the μ-oxo-hexaacetate-bis(4-methylpyridine)triruthenium nitrosyl complex

  摘要：

  The properties of the trinuclear cluster [RU3OAc6(Pic)(2)(NO)]PF6 (Pic = 4-methyl pyridine, Ac = acetate ion) and the photochemical behavior of the corresponding molecular films are reported in this paper. In this compound, the unpaired pi(*) electron from NO and the unpaired electron from the pi-orbitals of the Ru3O unity are strongly coupled; as a consequence, the changes in electronic distribution associated with the several successive redox states promote dramatic effects in the spectroscopic and electrochemical properties of the nitric oxide ligand and the entire complex. NO release has been observed by light irradiation (phi = 0.038 at 365 nm and phi = 0.019 at 468 nm, in acetonitrile solution), changing the original violet color into deep blue. The same behavior has been observed in solid state and in PVA films incorporating this compound, revealing its potential usefulness as NO photoreleaser, as well as for the monitoration of light exposure intensities. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.08.004

文献信息

• Ruthenium Acetate Cluster Amphiphiles and Their Langmuir–Blodgett Films for Electrochromic Switching Devices
  作者：Karine P. Naidek、Denize M. Hoffmeister、Jaqueline Pazinato、Eduard Westphal、Hugo Gallardo、Marcelo Nakamura、Koiti Araki、Henrique E. Toma、Herbert Winnischofer

  DOI：10.1002/ejic.201301442

  日期：2014.3

  We synthesized a long-chain phenylazopyridine ligand and used it to obtain three new amphiphilic trinuclear ruthenium acetate clusters. The amphiphilicity and anisometric form of the long-chain ligand allowed the complexes to self-assemble at the liquid–air interface and enabled their deposition by the Langmuir–Blodgett technique. We obtained the linear complex [Ru3O(C2H3O2)6(py)2L]+ [L = 4-(4-dod

  我们合成了一个长链苯基偶氮吡啶配体，并用它获得了三个新的两亲性三核乙酸钌簇。长链配体的两亲性和不等轴形式允许配合物在液-气界面自组装，并使其能够通过朗缪尔-布洛杰特技术沉积。我们得到了线性配合物 [Ru3O(C2H3O2)6(py)2L]+ [L = 4-(4-dodecyloxyphenylazo)pyridine, py = pyridine]，它比三角形的 [Ru3O( )6L3]+ 和更适合在电致变色开关器件中应用，正如其在近红外区域的快速开关和光学变化所证明的那样。事实上，我们的电致变色装置在数百个开关周期内保持稳定。