(η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate | 446281-70-5

• 英文名称: (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate
• CAS: 446281-70-5
• 化学式: CHCl₃*C₂₆H₂₉ClN₃PPdPtS₂
• 分子量: 934.973
• InChiKey: ZHDRASXBGGJPNC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 sodium bicarbonate 作用下， 以 甲醇 、 氯仿 为溶剂， 生成 (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate
  参考文献：
  名称：

  (η³-Allyl-2κ³C)(chloro-1κCl)(μ-N,N′-diethyldithioxamidato-1:2κ⁴S,S′:N,N′)[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate

  摘要：

  The title compound, [PdPtCl(C3H5)(C6H10N2S2)(C17H14NP)].- CHCl3, was obtained by deprotonation of the initial platinum(II) complex of the dithioxamide and subsequent reaction with [Pd(eta(3)-C3H5)(mu-Cl)](2). Both metal atoms exhibit a square-planar coordination geometry, with the two planes forming a dihedral angle of 21.7 (2)degrees. The dithioxamide bis-chelating bridge is flat.

  DOI：

  10.1107/s0108270102006303