Ga(tert-butyl)3(2,2-dimethyl-1,3-propanediamine) | 436854-15-8

• 英文名称: Ga(tert-butyl)3(2,2-dimethyl-1,3-propanediamine)
• CAS: 436854-15-8
• 化学式: C₁₇H₄₁GaN₂
• 分子量: 343.249
• InChiKey: MYHOMRRMPRLCMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Ga(tert-butyl)3(2,2-dimethyl-1,3-propanediamine) 、 三叔丁基镓 以 正己烷 为溶剂， 以52%的产率得到(Ga(tert-butyl)3)2(μ-2,2-dimethyl-1,3-propanediamine)
  参考文献：
  名称：

  Aluminum, gallium and copper complexes of 2,2-dimethyl-1,3-propanediamine

  摘要：

  Reaction of M('Bu)(3) (M = Al. Ga) with 2,2-dimethyl-1,3-propanediamine (dmpa-H-4) yields the thermally stable Lewis acid-base complexes ('Bu)(3)M(dmpa-H-4), M = Al (1) and Ga (2), respectively. The reaction of 2 with Ga('Bu)(3) yields the formation of [('Bu)(3)Ga](2)(dmpa-H-4) (3). In contrast, reaction of dmpa-H-4 with AlMe3 yields the tri-aluminum compounds [Al3Me5(dmpa-H-2)(2)] (4). Reaction of dmpa-H-4 With CuCl2 in MeOH-THF yields the neutral complex, [Cu(dmpa-H-4)(2)Cl-2] (5), While the reaction in the presence of NaBPh4 and MeCN yields the ionic complex [Cu(dmpa)(2)(MeCN)(2)][BPh4](2) (6). Compound 6 may also be formed directly from compound 5. The molecular structures of compounds 2-6 have been determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01151-2
• 作为产物：
  描述：

  二甲基丙二胺 、 三叔丁基镓 以 正戊烷 为溶剂， 以80%的产率得到Ga(tert-butyl)3(2,2-dimethyl-1,3-propanediamine)
  参考文献：
  名称：

  Aluminum, gallium and copper complexes of 2,2-dimethyl-1,3-propanediamine

  摘要：

  Reaction of M('Bu)(3) (M = Al. Ga) with 2,2-dimethyl-1,3-propanediamine (dmpa-H-4) yields the thermally stable Lewis acid-base complexes ('Bu)(3)M(dmpa-H-4), M = Al (1) and Ga (2), respectively. The reaction of 2 with Ga('Bu)(3) yields the formation of [('Bu)(3)Ga](2)(dmpa-H-4) (3). In contrast, reaction of dmpa-H-4 with AlMe3 yields the tri-aluminum compounds [Al3Me5(dmpa-H-2)(2)] (4). Reaction of dmpa-H-4 With CuCl2 in MeOH-THF yields the neutral complex, [Cu(dmpa-H-4)(2)Cl-2] (5), While the reaction in the presence of NaBPh4 and MeCN yields the ionic complex [Cu(dmpa)(2)(MeCN)(2)][BPh4](2) (6). Compound 6 may also be formed directly from compound 5. The molecular structures of compounds 2-6 have been determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01151-2