| 56800-89-6

• CAS: 56800-89-6
• 化学式: C₄₂H₄₁NOP₂RuS₂
• 分子量: 802.943
• InChiKey: LDFPYCOCIYAFEW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三氟甲磺酸 生成
  参考文献：
  名称：

  Synthesis and reactivity of nitrido-rhenium and -osmium complexes with an oxygen tripod ligand

  摘要：

  ReNCl3(PPh3)2] 或 [ReOCl2(PPh3)3] 与 NaLOEt（LOEt=[Co(η5-C5H5){PO(OEt)2}3]）反应，分别得到 [ReLOEtN(PPh3)Cl] 1 和 [ReLOEtOCl2] 2。将 1 与 AgBF4 反应，得到了硝化钌（VI）络合物 [ReLOEtN(PPh3)Cl]BF41-BF4，其 μeff 为 1.8 μB。用 MeOSO2CF3、PhCH2Br 或 [Ph3C]BF4 处理 1，可得到相应的有机亚氨基物种 [ReLOEt(NMe)(PPh3)Cl][CF3SO3] 3、[ReLOEt(NCH2Ph)(PPh3)Cl]Br 4 和 [ReLOEt(NCPh3)(PPh3)Cl] 5。将 1 与 [Au(PPh3)(CF3SO3)]、[Ru(Et2dtc)(PPh3)2(CO)(CF3SO3)] 或 [ReMeO3] 反应，可得到双金属氮化物配合物 [Au(PPh3){NReLOEt(PPh3)Cl}][CF3SO3] 6、分别为[Ru(Et2dtc)(PPh3)(H2O)(CO){NReLOEt(PPh3)Cl}][CF3SO3] 7 或[ReMeO3{NReLOEt(PPh3)Cl}] 8。用 NaLOEt 处理 [NBu4n][OsNCl4] 得到 [OsLOEtNCl2] 9。9 中的 Os-O、Os-Cl 和 Os-N 的平均距离分别为 2.066、2.289 和 2.58(1)埃。9 与 PPh3 反应后得到锇（IV）磷酰亚胺物种 [OsLOEt(NPPh3)Cl2]10，其 μeff 为 2.0 μB。10 中的 Os-O、Os-Cl 和 Os-N 的平均距离分别为 2.099、2.342 和 1.893(5)埃，Os-N-P 角为 137.5(3)°。LOEt-Re 和 -Os 复合物的形式电位是通过循环伏安法测定的。根据 ReVI-ReV 的形式电位，发现π-载体强度按照 N3- > [NAu(PPh3)]2- > NMe2- 的顺序递减。

  DOI：

  10.1039/a906618g

文献信息

• Organometallic chemistry of ethynyl boronic acid MIDA ester, HCCB(O₂CCH₂)₂NMe
  作者：Anthony F. Hill、Craig D. Stewart、Jas S. Ward

  DOI：10.1039/c4dt03695f

  日期：——

  The reactions of HCCBMIDA (BMIDA = B(O₂CCH₂)₂NMe) with a range of ruthenium complexes examples of σ-alkynyl, σ-alkenyl and vinylidene complexes bearing 4-coordinate boron substituents.

  HCCBMIDA（BMIDA = B（O₂CCH₂）₂NMe）与一系列钌配合物反应的结果是形成了具有4配位硼取代基的σ-炔基、σ-烯基和乙烯基配合物的示例。
• Alkyne insertion reactions of [RuH(κ2-S2CNEt2)(CO)(PPh3)2]: synthesis of alkenyl, alkynyl and enynyl complexes
  作者：Robin B Bedford、Catherine S.J Cazin

  DOI：10.1016/s0022-328x(99)00664-6

  日期：2000.3

  diethyldithiocarbamate hydride ruthenium complex [RuH(κ2-S2CNEt2)(CO)(PPh3)2] reacts with excess phenylacetylene to give the alkynyl complex [Ru(CCPh)(κ2-S2CNEt2)(CO)(PPh3)2] via the intermediate alkenyl complex [Ru(CHCHPh)(κ2-S2CNEt2)(CO)(PPh3)2] and with 1,4-diphenylbutadiyne to give the enynyl complex [Ruη1-C(CCPh)CHPh}(κ2-S2CNEt2)(CO)(PPh3)2]. The alkenyl complex [Ru(CHCHPh)(κ2-S2CNEt2)(CO)(PPh3)2]

  所述二乙基二氢化钌配合物[期RuH（κ 2 -S 2 CNET 2）（CO）（PPH 3）2 ]与过量的苯乙炔反应，得到炔基复杂的[Ru（CCPh）（κ 2 -S 2 CNET 2） （CO）（PPH 3）2 ]经由中间体烯复杂的[Ru（CHCHPh）（κ 2 -S 2 CNET 2）（CO）（PPH 3）2 ]和用1,4-二diphenylbutadiyne得到enynyl复杂的[Ru η 1 -C（CCPh）CHPh}（κ 2 -S 2 CNET 2）（CO）（PPH3）2 ]。烯基配合物的[Ru（CHCHPh）（κ 2 -S 2 CNET 2）（CO）（PPH 3）2 ]是该类型的复合物的炔基的便利前体的[Ru（CCR）（κ 2 -S 2 CNET 2）（CO）（PPH 3）2 ]（R =芳基，烷基，C 6 H ^ 4 -4-CCH）。
• Heterobimetallic μ-nitrido complexes containing ruthenium(II) dithiocarbamate
  作者：Hegen Zheng、Wa-Hung Leung、Joyce L.C Chim、Willetta Lai、Chong-Ho Lam、Ian D Williams、Wing-Tak Wong

  DOI：10.1016/s0020-1693(00)00169-9

  日期：2000.8

  Interaction of [Ru(Co)H(Et(2)dtc) with triflic acid (HOTf) afforded [Ru(Co)H(Et(2)dtc)(PPh3)(2)(OTf) (1), which has been characterized by X-ray crystallography. The Ru-C, Ru-O, average Ru-S and average Ru-P distances in 1 an 1.811(5), 2.216(3), 2.433 and 2.423 Angstrom, respectively. Reaction of 1 with amines L results in the formation of adducts trans-[Ru(CO)(Et(2)dtc)(PPh3)(2)L](OTf) (L = N2H4 (2) and NH2OH (3)). The Ru-C, Ru-N, average Ru-S and average Ru-P distance in 3 are 1.85(1), 2.179(8), 2.433 and 2.393, respectively; the Ru-N-O angle being 119.7(5)degrees. Treatment of 1 with [(NBu4)-Bu-n][OsN(C7H6S2)(2)] ([C7H6S2](2-) =3,4-toluenedithiolate(2-)), and [ReN(Et(2)dtc)(2)] (Et(2)dtc = N,N-diethyldithiocarbamate) gave the corresponding mu-nitrido complexes [Ru(CO)(Et(2)dtc)(PPh3)(2)(NOsO3)] (4), [Ru(CO)(Et(2)dtc)(PPh3)(2)NOs(C7H6S2)(2)}] (5) and [Ru(CO)(Et(2)dtc)(PPh3)(2)NRe(Et(2)dtc)(2)}] (6). The structures of complexes 4-6 have been established by X-ray crystallography. The Os-N and Ru-N distances, and Os-N-Ru angle in 4 are 1.719(7) and 2.075(7) Angstrom, and 155.1(4)degrees, respectively. The Os-N and Ru-N distances and Os-N-Ru angle in 5 are 1.680(6) and 2.068(6) Angstrom, and 166.2(3)degrees, respectively. The Re-N and Ru-N distances, and Re-N-Ru angle for 6 are 1.670(3) and 2.108(3) Angstrom, and 170.9(2)degrees, respectively. The bond lengths and angles for these mu-nitrido complexes are indicative of asymmetric bridging mode of nitride, i.e. M=N --> Ru(II) (M = Os(VIII), Os(VI), Re(V)). (C) 2000 Elsevier Science S.A. All rights reserved.