fac-(1,2-bis(diphenylphosphino)propane)tricarbonyl rhenium(I) hydride | 145247-36-5

• 英文名称: fac-(1,2-bis(diphenylphosphino)propane)tricarbonyl rhenium(I) hydride
• 英文别名: fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)hydridorhenium(I)；fac-Re(CO)3(1,2-bis(diphenylphosphino)propane)H
• CAS: 145247-36-5
• 化学式: C₃₀H₂₇O₃P₂Re
• 分子量: 683.697
• InChiKey: UFSBAQCEOBKTFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲酸 、 fac-(1,2-bis(diphenylphosphino)propane)tricarbonyl rhenium(I) hydride 以 二氯甲烷 为溶剂， 以93%的产率得到fac-Re(CO)3(1,2-bis(diphenylphosphino)propane)(formato)
  参考文献：
  名称：

  锰（I）和rh（I）配合物fac-（CO）3（dppp）MOC（H）O的合成和X射线结构

  摘要：

  的单核锰（I）和铼（I）formato络合物，FAC - （CO）3（DPPP）MOC（H）O（M =锰1 ; M = RE，2），已经从制备FAC - （CO）3（dppp）MH和甲酸，并确定其X射线结构。化合物1和2的不同之处在于，甲酰配体以末端单齿方式结合。对于Mn，先前仅通过X射线衍射表征了含有桥联甲酰基配体的多核络合物。所述MO键长和键MOC角度是2.043（2）和124.2（2）°，分别为1和2.167（3）和122.3（3）°，分别为2。化合物1和2也可以在高温下脱羧，同时定量回收fac-（CO）3（dppp）MH。

  DOI：

  10.1016/s0022-328x(99)00743-3
• 作为产物：
  描述：

  在 aq. KOH 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 fac-(1,2-bis(diphenylphosphino)propane)tricarbonyl rhenium(I) hydride
  参考文献：
  名称：

  The synthesis and reactions of ReI carboxylic acids. The X-ray structure of fac-Re(CO)3(dppp)CO2D·0.5C6D6

  摘要：

  The metallocarboxylic acids Re(CO)3(P-P)C(O)OH where (P-P) is either dppe [1,2-bis(diphenylphosphino)ethane] or dppp [1,3-bis(diphenylphosphino)propane] and their deuterio analogs have been prepared from the reaction of [Re(CO)4(P-P)]+ BF4- with NaOH(D) and characterized. Concentrated benzene solutions of the dppp complex deposit the acid as a dimer with 1 mol of solvated benzene and the X-ray crystal structure study of the deuterio dimer acid is reported. The cationic salts, 1, do not react with alcohols unless base is present. However, the acids are immediately esterified when they are dissolved in alcohols by virtue of the acids' spontaneous ionization through acyl-oxygen cleavage to the cation and hydroxyl anion; the latter abstracts a proton to give the conjugate base of the alcohol required for esterification. Solutions of the acids in DMSO undergo slow decarboxylation to the corresponding hydrides; addition of KOH to either DMSO or DMF solutions results in immediate decarboxylation.

  DOI：

  10.1016/0022-328x(92)80053-z

文献信息

• Reactions of dirhenium heptoxide with manganese(I) and rhenium(I) hydrido, alkoxo, methylcarbonato, carbonato-bridged, and methoxymethyl complexes. The X-ray structures of fac-(CO)3(dppp)MnOReO3 and fac-(CO)3(dppp)ReOReO3
  作者：Damon A. Brown、David M. Kimari、Anna M. Duzs-Moore、Theodore A. Budzichowski、Douglas M. Ho、Santosh K. Mandal

  DOI：10.1016/s0022-328x(02)01632-7

  日期：2002.9

  manganese(I) and rhenium(I) hydrido fac-(CO)3(PP)MH}, alkoxo fac-(CO)3(PP)MOR}, methylcarbonato fac-(CO)3(PP)MOC(O)OCH3}, carbonato-bridged [(CO)3(PP)M]2μ-OC(O)O} and methoxymethyl fac-(CO)3(PP)MCH2OCH3} complexes, where, R is CH3 or CH2CH3, PP is dppe 1,2-bis(diphenylphosphino)ethane} or dppp 1,3-bis(diphenylphosphino)propane}, yielded the corresponding perrhenato complexes, fac-(CO)3(PP)MOReO3

  再处理2 ö 7与锰（I）和铼（I）氢基 FAC - （CO）3，烷氧（PP）MH} FAC - （CO）3（PP）MOR}，methylcarbonato FAc-（CO）3（PP）MOC（O）OCH 3 }，羰基桥接的[（CO）3（PP）M] 2 μ-OC（O）O}和甲氧基甲基 FAc-（ CO）3（PP）MCH 2 OCH 3 }配合物，其中R为CH 3或CH 2 CH 3，PP为dppe 1,2-双（二苯基膦基）乙烷}或dppp 1,3-双（二苯基膦基）丙烷}，生成相应的perrhenato配合物FAc-（CO）3（PP）MOReO 3（1，M = Mn，PP= dppe; 2，M = Mn，PP= dppp; 3，M = Re，PP= dppe; 4，M = Re，PP= dppp），中等至极高的产量。所述perrhenato络合物已经光谱表征和的分子结构FAC
• The synthesis and reactions of Mn and Re formyl complexes, fac-(PP)M(CO)3CHO. The X-ray structure of fac-(dppp)Mn(CO)3CH2OCH3
  作者：Santosh K. Mandal、Jeanette A. Krause、Milton Orchin

  DOI：10.1016/0022-328x(94)88015-8

  日期：1994.3

  Treatment of the salts fac-[(P-P)M(CO)4][BF4] (M = Mn, Re; P-P = dppe, dppp) with NaBH4 gives the corresponding formyl complexes, fac-(P-P)M(CO)3CHO in excellent yield. Solutions of these formyls undergo spontaneous loss of CO to give the corresponding hydrides, fac-(P-P)M(CO)3H. On treatment with methyl triflate or protic acids the formyls undergo expected disproportionation reactions; the X-ray crystal structure determination of one of the products, fac-(dppp)Mn(CO)3CH2OCH3, is reported.