cobalt dinitrosyl | 263757-39-7

• 英文名称: cobalt dinitrosyl
• CAS: 263757-39-7
• 化学式: CoN₂O₂
• 分子量: 119.005
• InChiKey: BBQQOPPPLNYVQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氧化亚氮 、 钴 以 solid matrix 为溶剂， 生成 cobalt dinitrosyl
  参考文献：
  名称：

  激光烧蚀的 Fe、Co 和 Ni 与 NO 的反应：MNO+ 和 M(NO)x 的红外光谱和密度泛函计算 (M = Fe, Co, x = 1−3; M = Ni, x = 1, 2 ), 和 M(NO)x- (M = Co, Ni; x = 1, 2)

  摘要：

  Laser-ablated iron, cobalt, and nickel atoms, cations, and electrons have been reacted with NO molecules during condensation in excess neon and argon. The end-on bonded Fe(NO)(1-3), CO(NO)(1-3), and Ni(NO)(1-2) nitrosyls and side-bonded Fe-(eta(2)-NO), Co-(eta(2)-NO), and Ni-(eta(2)-NO) species are formed during sample deposition or on annealing. The FeNO+, CoNO+, and NiNO+ mononitrosyl cations are also produced via metal cation reactions with NO. Evidence is also presented for the Ni(NO)(1,2)- and Co(NO)(1,2)- anions. The product absorptions are identified by isotopic substitution ((NO)-N-15-O-16, (NO)-N-15-O-18 and mixtures), electron trapping with added CCl4, and density functional calculations of isotopic frequencies. This work provides the first vibrational spectroscopic characterization of Fe, Co, and Ni nitrosyl cations and anions.

  DOI：

  10.1021/jp993340j