(dichloromono-1-amidino-O-n-butylurea)copper(II) | 67825-92-7

• 英文名称: (dichloromono-1-amidino-O-n-butylurea)copper(II)
• CAS: 67825-92-7
• 化学式: C₆H₁₄Cl₂CuN₄O
• 分子量: 292.655
• InChiKey: RZHXUXUYJUHGRU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium sulfate 、 (dichloromono-1-amidino-O-n-butylurea)copper(II) 、 水 以 水 为溶剂， 以79%的产率得到bis(dichloromono-1-amidino-O-n-butylurea)copper(II) sulfate dihydrate
  参考文献：
  名称：

  Spectroscopic studies on bis(1-amidino-O-alkylurea) copper(II) sulfate complexes where alkyl=methyl, ethyl, n-propyl or n-butyl: EPR evidence for binuclear complexes

  摘要：

  Four new Cu(II) Complexes viz [Cu(II)(1-amidino-O-methylurea)(2)]SO4 2H(2)O (1), [Cu(II)(1-amidino-O-ethylurea)(2)](SO4)(2) 2H(2)O (2), [Cu(II)(1-amidion-O-n-propylurea)(2)]SO4 2H(2)O (3). [Cu(II)(1-amidino-O-n-butylurea)(2)](2)(SO4)(2) 2H(2)O (4) have been synthesized and characterized EPR spectrum of complex 4 at RT consisted of fine-structure transitions (Delta Ms = +/- 1) with zero-field splitting (ZFS) of 0 0485 cm(-1) and a half-field signal (Delta MS = +/- 2) at ca 1600 G, revealed formation of binuclear complex (S = 1) Whereas EPR spectrum of complex 2 in DMSO showed a mixture of mononuclear and binuclear complex in the ratio 0 75: 1.0 with ZFS of 0.0385 cm(-1) From the temperature dependence of the EPR signal intensity, the isotropic exchange-interaction constant J was evaluated. (C) 2009 Elsevier B V. All rights reserved

  DOI：

  10.1016/j.inoche.2009.12.023
• 作为产物：
  描述：

  copper(II) choride dihydrate 、 正丁醇 、 二聚氰胺 以 正丁醇 为溶剂， 生成 (dichloromono-1-amidino-O-n-butylurea)copper(II)
  参考文献：
  名称：

  Spectroscopic studies on bis(1-amidino-O-alkylurea) copper(II) sulfate complexes where alkyl=methyl, ethyl, n-propyl or n-butyl: EPR evidence for binuclear complexes

  摘要：

  Four new Cu(II) Complexes viz [Cu(II)(1-amidino-O-methylurea)(2)]SO4 2H(2)O (1), [Cu(II)(1-amidino-O-ethylurea)(2)](SO4)(2) 2H(2)O (2), [Cu(II)(1-amidion-O-n-propylurea)(2)]SO4 2H(2)O (3). [Cu(II)(1-amidino-O-n-butylurea)(2)](2)(SO4)(2) 2H(2)O (4) have been synthesized and characterized EPR spectrum of complex 4 at RT consisted of fine-structure transitions (Delta Ms = +/- 1) with zero-field splitting (ZFS) of 0 0485 cm(-1) and a half-field signal (Delta MS = +/- 2) at ca 1600 G, revealed formation of binuclear complex (S = 1) Whereas EPR spectrum of complex 2 in DMSO showed a mixture of mononuclear and binuclear complex in the ratio 0 75: 1.0 with ZFS of 0.0385 cm(-1) From the temperature dependence of the EPR signal intensity, the isotropic exchange-interaction constant J was evaluated. (C) 2009 Elsevier B V. All rights reserved

  DOI：

  10.1016/j.inoche.2009.12.023