| 334798-84-4

• CAS: 334798-84-4
• 化学式: C₅H₅FeN₂
• 分子量: 148.955
• InChiKey: VGQZLYBNRZJONS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η5-cyclopentadienyl)Fe(1+) 、 氮 以 gaseous matrix 为溶剂， 生成
  参考文献：
  名称：

  Dinitrogen addition to c-C5H5Fe+, C6H6Fe+ and FeO+ in the gas phase

  摘要：

  Results of an experimental study using the selection-ion flow tube technique are reported for reactions of bare Fe+ and iron containing FeX(+) cations (X = C6H6 (or B), c-C5H5 (or Cp), O, (Cp)(2), B-2) with dinitrogen at 294 +/- 3 K and at a helium buffer-gas pressure of 0.35 +/- 0.01 Torr. Fe+, B2Fe+ and Cp(2)Fe(+) do not react with dinitrogen. A very slow sequential addition of two N-2 molecules was observed with FeO+. CpFe(+) and BFe+ reacted without the subsequent addition of a second N-2 molecule. These results provide insight into the bonding of N-2 as a ligand with Fe as the coordination centre in the gas-phase, and into intrinsic kinetic aspects of dinitrogen addition.

  DOI：

  10.1016/0009-2614(95)00547-h