phenyl tert-butoxyl nitroxide | 42929-94-2

• 英文名称: phenyl tert-butoxyl nitroxide
• CAS: 42929-94-2
• 化学式: C₁₀H₁₄NO₂
• 分子量: 180.227
• InChiKey: KWXLVUBYQAQHQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  phenyl-peroxycarbamic acid tert-butyl ester 在 二叔丁基过氧化物 作用下， 以 苯 为溶剂， 生成 phenyl tert-butoxyl nitroxide
  参考文献：
  名称：

  Nitrogen-centered free radicals. VI. Electron spin resonance studies of N-alkoxy-N-alkylamino, N-alkoxy-N-arylamino, and N-alkoxy-N-carboethoxyamino radicals in solution

  摘要：

  DOI：

  10.1021/ja00798a045

文献信息

• The photochemically induced oxidation of aniline by hydroperoxides: An electron paramagnetic resonance study. Part II.
  作者：Loris Grossi

  DOI：10.1016/s0040-4020(01)85525-3

  日期：——

  The oxidation reaction of aniline by tertiary hydroperoxides, induced photochemically, was studied. The peculiar radical intermediates, nitroxides and peroxy radicals, involved in the reaction mechanism were detected and identified by EPR spectroscopy. The presence of these intermediates confirm that PhNO is the first product of the oxidation of aniline and the PhNH· radical as its precursor.

  研究了光化学诱导的叔氢过氧化物对苯胺的氧化反应。通过EPR光谱法检测并鉴定了参与反应机理的特殊自由基中间体，氮氧化物和过氧自由基。这些中间体的存在证实了PhNO是苯胺和PhNH·自由基作为其前体氧化的第一产物。
• New nitrogen containing radicals from nitro and organometallic compounds: R′-NO·-OMR3, (R′=ARYL, ALKYL), Ar-N•-OMR3, and Ar-N(OMR3)-N•Ar (M=Si,Ge,Sn)
  作者：Knud Reuter、Wilhelm P. Neumann

  DOI：10.1016/s0040-4039(01)85859-7

  日期：1978.1