[(1-3-η)cycloocta-2-en-1-yl](2-[N-(2,6-dimethylphenyl)imino-κN-methyl]pyrrolide-κN)nickel | 1103521-61-4

• 英文名称: [(1-3-η)cycloocta-2-en-1-yl](2-[N-(2,6-dimethylphenyl)imino-κN-methyl]pyrrolide-κN)nickel
• CAS: 1103521-61-4
• 化学式: C₂₁H₂₆N₂Ni
• 分子量: 365.141
• InChiKey: QLIJIBGFTFZRPG-HOUBHPSFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 2-{N-(2,6-dimethylphenyl)iminomethyl}-pyrrole 以 氘代苯 为溶剂， 生成 [(1-3-η)cycloocta-2-en-1-yl](2-[N-(2,6-dimethylphenyl)imino-κN-methyl]pyrrolide-κN)nickel
  参考文献：
  名称：

  Synthesis of 2-(N-arylimino-κN-methyl)pyrrolide-κN complexes of nickel

  摘要：

  2-(N-aryliminomethyl) pyrrole precursors (2,6-R-2-C6H3-N=CH-2-C4H3NH) (R = Me, IH; R = Pr-i, IIH) were prepared and transformed into their corresponding sodium salts (Na+I and Na+II) by treatment with NaH. Both salts readily react with [NiBr2(DME)] (DME = 1,2- dimethoxyethane) to give the respective bis{2-(N-arylimino-kappa N-methyl) pyrrolide-kappa N} nickel(II) complexes (1, 2) in almost quantitative yields. The oxidative addition of IH to [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) results in the formation of 3, which is a mono(iminomethylpyrrolide)-eta(3)-(cyclic-allyl)-type organonickel(II) complex. The crystal structure of compound 1 has been established by X-ray diffraction studies. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.09.067