[(tetramethylene sulfoxide)H]+[trans-Ru(tetramethylene sulfoxide-S)2Cl4]- | 132834-40-3

• 英文名称: [(tetramethylene sulfoxide)H]+[trans-Ru(tetramethylene sulfoxide-S)2Cl4]-
• 英文别名: [(TMSO)H]⁺[trans-Ru(TMSO-S)₂Cl₄]^-；[(tetramethylenesylfoxide)H][trans-RuCl4(tetramethylene sulfoxide)2]
• CAS: 132834-40-3
• 化学式: C₄H₈OS*C₈H₁₆Cl₄O₂RuS₂*H
• 分子量: 556.409
• InChiKey: YAKYXBRECATPLY-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,2'-联吡啶 、 [(tetramethylene sulfoxide)H]+[trans-Ru(tetramethylene sulfoxide-S)2Cl4]- 在 tetramethylene sulfoxide 作用下， 以 丙酮 为溶剂， 以99%的产率得到mer-[RuCl3(tetramethylene sulfoxide)(2,2'-bipyridine)]
  参考文献：
  名称：

  Unexpected formation and structure elucidation of mer-[RuCl3(TMSO)(bpy)] derived from [H(TMSO)][trans-RuCl4(TMSO)2] under mild condition

  摘要：

  Treatment of [H(TMSO)][trans-RUCl4(TMSO)(2)] (1) with 2,2'-bipyridine (bpy) in ethanol at room temperature resulted an unknown mer-[RuCl3(TMSO)(bpy)] (3) and a known cis-[RuCl2(TMSO)(4)] (4) (TMSO = tetramethylene sulfoxide) complexes. The 3 was obtained by the substitution with bpy in mer-[RuCl3(TMSO)(3)] (2), whereas 4 was obtained by one-electron reduction of 2, suggesting that 2 is a precursor for both 3 and 4. The structure of 3 was determined by single crystal X-ray diffraction. The reaction is a new synthetic procedure for 3 and/or 3 and 4 in mild reaction conditions from the anionic complex 1. It involves simultaneous substitution and redox reaction. This is the first known example of precisely characterized Ru(III)-chloride-TMSO-bpy-complex derived from anionic [H(TMSO)][trans-RuCl4(TMSO)(2)] at room temperature. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.040

文献信息

• Synthesis and crystal structures of carbonyl derivatives of chloride–tetramethylene sulfoxide–ruthenium(III) complexes: [RuCl3(TMSO)2(CO)] and [H(TMSO)2] [RuCl4(TMSO)(CO)]
  作者：Radhey S Srivastava、Frank R Fronczek

  DOI：10.1016/s0020-1693(01)00529-1

  日期：2001.10

  [H(TMSO)][RuCl4(TMSO)2] with carbon monoxide in the presence or absence of TMSO at ambient temperature and pressure. Complexes 1 and 2 represents the first examples of Ru(III) compounds bearing both tetramethylene sulfoxide and carbon monoxide ligands on the metal. Substitution of one of the two trans-S-bonded TMSO from the anion accompanied addition of one molecule of TMSO on the cation. Coordination of CO induces

  报道了[RuCl 3（TMSO）2（CO）]（1）和[H（TMSO）2 ] [RuCl 4（TMSO）（CO）]（2）的合成，光谱表征和晶体结构。这些配合物是通过在环境温度和压力下，在存在或不存在TMSO的情况下，将前体[ mer -RuCl 3（TMSO）3 ]和[H（TMSO）] [RuCl 4（TMSO）2 ]与一氧化碳反应制备的。 。配合物1和2代表在金属上同时带有四亚甲基亚砜和一氧化碳配体的Ru（III）化合物的第一个实例。阴离子上两个反式-S键合的TMSO之一被取代，同时在阳离子上添加了一个TMSO分子。CO的配位诱导TMSO配体的S-O键异构化。1的晶体是橘红色的针状单斜晶体，空间群C 2 / c，a = 26.446（2）Å，b = 8.8726（6）Å，c = 15.1093（8）Å，β = 107.427（4） °。的晶体2是橙色针，斜方晶系，空间群晶Pnma，一个= 11
• A study on tailor made ruthenium sulfoxide complexes: Synthesis, characterization and application
  作者：Ripul Mehrotra、Satyendra Shukla、Pratiksha Gaur

  DOI：10.2298/jsc140704086m

  日期：——

  In this study, a dinucleating spacer incorporating two 2-aminopyridine units was used to prepare seven novel dinuclear compounds. These molecules were characterized by elemental analyses, conductivity measurements, magnetic susceptibility, FT-IR, FAB-Mass, electronic, H-1-NMR and C-13H-1}-NMR spectral studies. The complex [trans,mer-RuCl2(DMSO)(3)}(2)(mu-5,5'-methylenebis(2-aminopyridine))]center dot 2DMSO (2) was also characterized through H-1-H-1 COSY NMR. There are mainly three different formulations, [cis,fac-RuCl2( SO)(3)}(2)(mu-MBAP)]center dot 2SO; [trans,mer-RuCl2(SO)(3)}(2)(mu-MBAP)]center dot 2SO and [trans-RuCl4(SO)}(2)(mu-MBAP)](2-) [X](2)(+); where SO = DMSO / TMSO; MBAP = 5,5'-methylenebis(2-pyridinamine) and [X](+) = [(DMSO)(2)H](+), Na+ or [(TMSO)H](+). The coordination was found through cyclic nitrogen of the pyridine ring in an octahedral environment for both metal centres. The chemical behaviour of [cis, fac-RuCl2(DMSO)(3)}(2)(mu-5,5'-methylenebis(2-pyridinamine))]center dot 2DMSO (1) and (2) in aqueous solution with respect to time was observed by conductivity measurements and UV-Vis spectrophotometry. All complexes were found to possess prominent antibacterial activity against Escherichia coli in comparison to chloramphenicol and gatifloxacin.