[(2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine)PdClC(O)Me] | 1157859-47-6

• 英文名称: [(2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine)PdClC(O)Me]
• CAS: 1157859-47-6
• 化学式: C₁₃H₁₆ClN₃OPd
• 分子量: 372.163
• InChiKey: JAURSAPLPDJPMI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  一氧化碳 、 [(2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine)PdClMe] 以 氘代氯仿 为溶剂， 生成 [(2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine)PdClC(O)Me]
  参考文献：
  名称：

  (Pyrazol-1-ylmethyl)pyridine palladium complexes: Synthesis, molecular structures, and activation of small molecules

  摘要：

  Reactions of 2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine (L1) and 2-(3,5-di-tert-butylpyrazol-1-ylmethyl)pyridine (L2) with either [PdClMe(COD)] or [PdCl2(COD)] gave the mononuclear palladium complexes [PdCl2(L1)] (1), [PdClMe(L1)] (2) [PdCl2(L2)] (3) and [PdClMe(L2)] (4) in good yields. All compounds were characterized by NMR spectrometry, mass spectrometry, elemental analyses and also by single crystal X-ray crystallography for complexes 1, 3, and 4. The reaction of 2 with NaBAr4 in NCMe gave the salt, [[PdMeNCMe(L3)] BAr4 (5), in good yield. This salt was used as a catalyst to oligomerize ethylene at high pressures to branched polyethylene, but catalytic activity was low. The reaction of 2 with SO2 and CO formed the respective insertion products [PdClS(O)(2)Me(L1)] (6) and [PdClC(O) Me(L1)] (7). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.12.043