Mo(CO)3(2,2'-bipyridine)(HgCl)Cl | 22026-80-8

• 英文名称: Mo(CO)3(2,2'-bipyridine)(HgCl)Cl
• CAS: 22026-80-8
• 化学式: C₁₃H₈Cl₂HgMoN₂O₃
• 分子量: 607.654
• InChiKey: VQAZFAKWDRBGKN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Mo(CO)3(2,2'-bipyridine)(HgCl)Cl 、 tin(II) bromide 以 甲醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Reactivity of carbonyl complexes containing MoHg bonds; reaction of tin(II) halides with [Mo(CO)3(NN)(HgX)(X)] (NN = bpy, phen, dmp); crystal structure of [Mo(CO)3(dmp)(HgCl)(Cl)]

  摘要：

  Reaction of HgCl2 with [Mo(CO),(dmp)] (dmp = 2,9-dimethyl-1,10-phenanthroline) gives the heterobimetallic compound [MO(CO)3(dmp)(HgCl)(Cl)] (I), which gives rise to a new compound [Mo(CO)3(dmp)(HgCl)(Cl)] . 1/2(CH3)2CO (II) in acetone solution at low temperature. The crystal structure of I has been solved and the compound shown to be a capped trigonal prism containing Mo-Hg-Cl and Mo-Cl bonds. The reactions of the above and related heteronuclear complexes [MO(CO)3(NN)(HgX)(X)] [X = Cl, Br; NN = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen)] with tin (II) halides were studied. No insertion of the latter into the metal-metal or metal-halogen bonds were observed, with only bimetallic tricarbonyl complexes containing Mo-Hg bonds being isolated.

  DOI：

  10.1016/s0277-5387(00)80095-9
• 作为产物：
  描述：

  、 mercury dichloride 以 丙酮 为溶剂， 生成 Mo(CO)3(2,2'-bipyridine)(HgCl)Cl
  参考文献：
  名称：

  具有MoHg键的羰基配合物的反应性。钼（0）的三羰基配合物与硫脲和氯化汞的相互作用

  摘要：

  将硫脲添加到NNMo（CO）3（HgCl）（Cl）型（NN = 2,2'-联吡啶（bipy）; 1,10-菲咯啉（phen）; 2,9-二甲基-1,10-菲咯啉（dmp））产生保留MoHg键的新型化合物。

  DOI：

  10.1016/0022-328x(86)80227-3

文献信息

• Reactions of tricarbonyl phosphine complexes of molybdenum(0) with mercury chloride
  作者：M. Panizo、M. Cano

  DOI：10.1016/0022-328x(84)80137-0

  日期：1984.5

  The reactions of tricarbonylphosphine complexes (bipy)(P)Mo(CO)3, (bipy)= 2,2′-bipyridine and (P) = P(4-ClC6H4)3, P(4-FC6H4)3, P(4-CH3C6H4)3 and P(4-CH3OV6H4)3, with HgCl2 give compounds of the type (bipy)2Mo2(CO)6·HgCl2 and (bipy)Mo(CO)3(HgCl)(Cl), depending on the mol ratio of reactants employed. The reaction proceeds with elimination of the phosphine ligand and the coordination of HgCl2 to molybdenum

  三羰基膦配合物（bipy）（P）Mo（CO）3，（bipy）= 2,2'-联吡啶和（P）= P（4-ClC 6 H 4）3，P（4-FC 6 H 4）3，P（4-CH 3 C 6 H 4）3和P（4-CH 3 OV 6 H 4）3与HgCl 2一起生成（bipy）2 Mo 2（CO）6 ·HgCl类型的化合物2和（Bipy）Mo（CO）3（HgCl）（Cl），取决于所用反应物的摩尔比。该反应在消除膦配体和使HgCl 2与钼配位的情况下进行。
• The insertion of the [M(CO)3(NN)] fragments (M = Mo, W; NN = 2,2′-bipyridine; 1,10-phenanthroline; ethylenediamine) into the HgX (X = Cl, Br, I, N3, SCN) bonds of the [η5-C5H5Fe(CO)2(HgX)] complexes. Heterotrimetallic compounds with FeHgMX bondings
  作者：J. Granifo、M.E. Vargas

  DOI：10.1016/s0277-5387(00)80322-8

  日期：1989.1