[((p-bromophenyl)(phenyl)4C5)2Fe](1+) | 851681-82-8

• 英文名称: [((p-bromophenyl)(phenyl)4C5)2Fe](1+)
• CAS: 851681-82-8
• 化学式: C₇₀H₄₈Br₂Fe
• 分子量: 1104.81
• InChiKey: SCPBJWBZLNCRBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1',2,2',3,3',4,4'-octaphenyl-5,5'-di-p-bromophenyl-ferrocene 在 NOPF₆ 、 (butyl)4NPF₆ 作用下， 以 二氯甲烷 为溶剂， 生成 [((p-bromophenyl)(phenyl)4C5)2Fe](1+)
  参考文献：
  名称：

  Voltammetric Studies on Decaphenylferrocene, Substituted Decaphenylferrocenes, and Their Oxidized Forms in Dichloromethane and Ionic Liquids

  摘要：

  Cyclic voltammetric studies have been undertaken on highly insoluble decaphenylferrocene (DPFc), on substituted forms of the compound [methyl (Me(2)DPFc, Me(6)DPFc, and Me(10)DPFc), bromide (Br(2)DPFc), and ethynyl (Ethin(2)DPFc)], and on their more soluble one-electron-oxidized DPFc(+) forms. Studies with DPFc(+) and its derivatives dissolved in dichloromethane (DCM) enable the reversible potentials (E-0') of one-electron reduction processes, DPFc(+)(DCM) + e(-) reversible arrow DPFc(DCM), to be established. E-0' values obtained from these measurements exhibit the expected substituent dependence. Voltammetric studies with arrays of insoluble DPFc microparticles adhered to an electrode surface in contact with DCM (0.1 M Bu4NPF6) or ionic liquids are connected to the oxidized solid or dissolved forms of DPFc(+) via a range of pathways that are determined by the kinetics and thermodynamics of dissolution and reprecipitation processes. Comparative data obtained with more soluble ferrocene, ferricinium, and decamethylferrocene microparticles support the hypothesis that dissolution processes play an important role in determining the nature of the voltammetric response of adhered microparticles.

  DOI：

  10.1021/om049117c