trans-{RuCl2(CO)2(C6H15P)2} | 97335-31-4

• 英文名称: trans-{RuCl2(CO)2(C6H15P)2}
• 英文别名: trans-[RuCl2(CO)2(PEt3)2]
• CAS: 97335-31-4
• 化学式: C₁₄H₃₀Cl₂O₂P₂Ru
• 分子量: 464.315
• InChiKey: ZPMVDIYIXRUKNF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-{RuCl2(CO)2(C6H15P)2} 、 4-乙炔基苯胺 在 n-C₄H₉Li 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 以24%的产率得到all trans-[Ru(CO)2(PEt3)2(p-ethynyl anilinato)2]
  参考文献：
  名称：

  para-Ethynyl aniline as a building block for fully π-conjugated ligands and acetylide complexes: crystal structures of trans-[Pt(PPh3)2(CCC6H4NH2)2] and [(μ-H)Ru3(CO)9(μ3-CCC6H4NH2)]

  摘要：

  para-Ethynyl aniline has been prepared, structurally characterised and investigated as a building block towards fully pi -conjugated multifunctional ligands and complexes. Palladium-copper catalysed coupling with aryl halides affords a number of new amino-substituted aryl acetylenes, while using [Ni(CO)(2)(PPh3)(2)] as a catalyst, cyclotrimerisation and dimerisation to give an ene-yne were competitive. Reaction of para-ethynyl aniline with low-valent metal centres affords acetylide complexes trans[Pt(PR3)(2)(C=CC6H4NH2)(2)] (R = Ph, Bu-n), cis-[Pt(eta (2)-dppe)(C=CC6H4NH2)(2)], all trans-[Ru(CO)(2)(PEt3)(2)(C=CC6H4NH2)(2)] and [(muH)Ru-3(CO)(9)(mu C-3=CC6H4NH2)]. The bis(acetylide) trans-[Pt(PPh3)(2)(C=CC6H4NH2)(2)] has been used to prepare extended chain complexes with amide, imine, imino-phosphorane and ferrocenyl imine units being generated. Attempts to prepare polymers via reaction with terephthaloyl chloride lead only to the formation of oligomers with an average of four monomer units. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00254-1
• 作为产物：
  描述：

  dichlorotricarbonylruthenium(II) dimer 、 三乙基膦 以 四氢呋喃 为溶剂， 生成 trans-{RuCl2(CO)2(C6H15P)2}
  参考文献：
  名称：

  Cotton, J. D.; Bruce, M. I.; Stone, F. G. A., Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1968, p. 2162 - 2165

  摘要：

  DOI：

文献信息

• Competition between Steric and Electronic Control of Structure in Ru(CO)₂L₂L‘ Complexes
  作者：Masamichi Ogasawara、Feliu Maseras、Nuria Gallego-Planas、Kazumori Kawamura、Kazuhiko Ito、Koichiro Toyota、William E. Streib、Sanshiro Komiya、Odile Eisenstein、Kenneth G. Caulton

  DOI：10.1021/om9700775

  日期：1997.4.1

  simply Ru(η2-O2)(CO)2L2, but for Ru(CO)2(PEt3)3, this is accompanied by an apparent bimolecular electron transfer involving the intact complex to give Ru(CO)(CO3)(PEt3)3. X-ray structure determinations of Ru(CO)2(PEt3)3 (bis equatorial CO in trigonal bipyramid (TBP)), Ru(CO)2(PiPr2Me)3 (two isomers:  bis axial CO in TBP and also square pyramidal), and Ru(η2-PhCCPh)(CO)2(PEt3)2 (cis carbonyls and trans phosphines)

  在THF中存在等摩尔L的情况下，RuCl 2（CO）2 L 2的镁还原得到Ru（CO）2 L 3（L = PPh 3（1），PMePh 2（2），PEt 3（3），P iPr 2 Me（4））。在等摩尔L'（L'= P（2-呋喃基）3（5）或AsPh 3（6））存在下，RuCl 2（CO）2（PEt 3）2相应还原，得到Ru（CO）2（ PET 3）2 L '但给人的Ru（CO）的混合物2（PET 3）3 - ñ大号ñ（ñ = 0-3）物种当L'= PPH 3。比较显示3或5发生反应缓慢地用L ''=（H）2，CO，或光子晶体⋮器CPh形成的Ru（CO）2 L ''（PET 3）2和自由PET 3或P（2-呋喃基）3，但迅速与4或6给出类似产品。对于L'= PEt 3，PhC PhCPh与Ru（CO）2（PEt 3）2 L'的反应比对P（2-呋喃基）3的反应更快。所有这些反应，提出了用L的
• Reactions of trans-[RuCl2(CO)2(PEt3)2] with 1,1-dithiolates: Stepwise formation of cis-[Ru(CO)(PEt3)(S2X)] (X=CNMe2, CNEt2, COEt, P(OEt)2, PPh2)
  作者：Anthony J. Deeming、Caroline Forth、Graeme Hogarth

  DOI：10.1016/j.jorganchem.2005.08.051

  日期：2006.1

  (iii) loss of a phosphine. Thermolysis of cis-[Ru(CO)(PEt3)(S2CNMe2)2] with Ru3(CO)12 in xylene affords trinuclear [Ru3(μ3-S)2(PEt3)(CO)8] as a result of dithiocarbamate degradation. Crystal structures of cis-[Ru(CO)(PEt3)(S2X)2] (X = NMe2, COEt), trans-[Ru(PEt3)2Cl(CO)S2P(OEt)2}], trans-[Ru(PEt3)2(CO)(η1-S2COEt)(η2-S2COEt)] and [Ru3(μ3-S)2(PEt3)(CO)8] are reported.

  反式-[RuCl 2（CO）2（PEt 3）2 ]与一系列1,1-二硫代盐配体的两个当量反应形成双（二硫代盐）配合物，顺式-[Ru（CO）（PEt 3）（ S 2 X）2 ]（X ＝ CNMe 2，CNEt 2，COEt，P（OEt）2，PPh 2）。分离出了两种中间体。反式- [茹（PET 3）2 Cl（上CO）S 2 P（OET）2 }]和反式- [茹（PET 3）2（CO）（η 1-S 2 COET）（η 2 -S 2 COET）]，允许一个简单的反应方案涉及三个步骤假定; （i）初始取代顺式羰基和氯化物配体，（ii）取代第二种氯化物，（iii）失去膦。热解的顺式- [钌（CO）（PET 3）（S 2 CNME 2）2 ]与孺3（CO）12在二甲苯，得到三核的[Ru 3（μ 3 -S）2（PET 3）（CO）8二硫代氨基甲酸酯降解的结果。顺式的晶体结构-[Ru（CO）（PEt 3）（S
• Octahedral bis(acetylide) and bis(diacetylide) complexes of ruthenium(II) with linear C2MC2 and C4MC4 chains: The first X-ray structures of the all trans bis(acetylides) Ru(CO)2(CCPh)2(PEt3)2 and Ru(CO)2(CCH)2(PEt3)2
  作者：Yan Sun、Nicholas J. Taylor、Arthur J. Carty

  DOI：10.1016/0022-328x(92)83138-8

  日期：1992.1

  Bis(acetylides) and bis(diacetylides) of ruthenium(II), trans-Ru(CO)2(PEt3)2(CCR)2 (1) (1a, R  Ph; 1b, R  tBu; 1c, R  SiMe3; 1d, R  H) and trans-Ru(CO)2(PEt3)2(CCC CR)2 (2) (2a, R  SiMe3; 2b, R  H) have been synthesized and characterised. The first single crystal X-ray analyses of these all trans-acetylides have revealed linear C2RuC2 chains in 1a and 1d.

  二钌（乙炔化物）和双（diacetylides）（II），反式-Ru（CO）2（PET 3）2（CCR）2（1）（图1A，RPh值;图1b，R吨卜; 1C，R森达3 ; 1D，RH）和反式-Ru（CO）2（PET 3）2（CCCCR）2（2）（图2a，R森达3 ;图2b，R RH）已被合成和表征。所有这些反式乙炔化物的首次单晶X射线分析表明，在1a和1d中存在线性C 2 RuC 2链。
• Die darstellung von [(CH3)3PRu(CO)2Cl2]2 und [(Ch3)3P]2Ru(CO)2Cl2; Eine berichtigung zu: Die alkoholyse des triethylsilans katalysiert von [(Ch3)3P]2Ru(CO)2Cl2
  作者：J. Lippold、H. Singer

  DOI：10.1016/0022-328x(84)80116-3

  日期：1984.4

  The ruthenium(II) complex used as a catalyst in reactions of alcohols and Et3SiH proved to be the dimer [(CH3)3PRu(CO)2Cl2]2 and not the complex [(CH3)3P]2 Ru(CO)2Cl2. Both complexes were prepared, characterized and their catalytic properties were compared.

  在醇与Et 3 SiH反应中用作催化剂的钌（II）配合物被证明是二聚体[（CH 3）3 PRu（CO）2 Cl 2 ] 2而不是配合物[（CH 3）3 P] 2 Ru（CO）2 Cl 2。两种配合物均已制备，表征并比较了其催化性能。
• Lupin, M. S.; Shaw, B. L., Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1968, p. 741 - 749
  作者：Lupin, M. S.、Shaw, B. L.

  DOI：——

  日期：——