[Ru(1,3-bis(2-imidazoline-2-yl)benzene)(2,2':6',2''-terpyridine)]PF6 | 1000056-07-4

• 英文名称: [Ru(1,3-bis(2-imidazoline-2-yl)benzene)(2,2':6',2''-terpyridine)]PF6
• CAS: 1000056-07-4
• 化学式: C₂₇H₂₄N₇Ru*F₆P
• 分子量: 692.569
• InChiKey: SBXBFTGJQJSDRC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(1,3-bis(2-imidazoline-2-yl)benzene)(2,2':6',2''-terpyridine)]PF6 以 not given 为溶剂， 生成 [Ru(1,3-bis(2-imidazolyl)benzene)(2,2':6',2''-terpyridine)]PF6
  参考文献：
  名称：

  Aerobic oxidative dehydrogenation of coordinated imidazoline units of pincer ruthenium complex

  摘要：

  A new pincer ruthenium complex (1; [RuL1(tpy)](PF6); L-1 = 1,3- di(2-imidazoline-2-yl) benzene, tpy = 2,2': 6',2 ''- terpyridine) having a kappa(NCN)-N-3 pincer ligand with two imidazoline units and related ruthenium complexes were synthesized and characterized. The imidazoline units of 1 were oxidized in air to give an imidazole-ligated pincer complex (2; [RuL2(tpy)](PF6); L-2 = 1,3- di(2-imidazolyl) benzene). Results of the H-1 NMR spectroscopic and cyclic voltammetric studies of the complexes indicate that the sigma-donor character of the pincer ligand of 1 induces the Ru-promoted oxidative dehydrogenation of coordinated imidazoline moieties to imidazole units with oxygen in air. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.08.030
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 六氟磷酸银 、 Ru(tpy)(Cl)₃ 、 1,3-bis(4,5-dihydro-1H-imidazol-2-yl)benzene 以 乙二醇甲醚 为溶剂， 以13%的产率得到[Ru(1,3-bis(2-imidazoline-2-yl)benzene)(2,2':6',2''-terpyridine)]PF6
  参考文献：
  名称：

  Aerobic oxidative dehydrogenation of coordinated imidazoline units of pincer ruthenium complex

  摘要：

  A new pincer ruthenium complex (1; [RuL1(tpy)](PF6); L-1 = 1,3- di(2-imidazoline-2-yl) benzene, tpy = 2,2': 6',2 ''- terpyridine) having a kappa(NCN)-N-3 pincer ligand with two imidazoline units and related ruthenium complexes were synthesized and characterized. The imidazoline units of 1 were oxidized in air to give an imidazole-ligated pincer complex (2; [RuL2(tpy)](PF6); L-2 = 1,3- di(2-imidazolyl) benzene). Results of the H-1 NMR spectroscopic and cyclic voltammetric studies of the complexes indicate that the sigma-donor character of the pincer ligand of 1 induces the Ru-promoted oxidative dehydrogenation of coordinated imidazoline moieties to imidazole units with oxygen in air. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.08.030