1-(3-salicyliminopropyl)silatrane | 125232-70-4

• 英文名称: 1-(3-salicyliminopropyl)silatrane
• CAS: 125232-70-4；1357116-04-1
• 化学式: C₁₆H₂₄N₂O₄Si
• 分子量: 336.463
• InChiKey: NZVSXVFCUAVUEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-氨基丙基三乙氧基硅烷 以 甲醇 、 甲苯 、 正丁醇 为溶剂， 反应 6.0h， 生成 1-(3-salicyliminopropyl)silatrane
  参考文献：
  名称：

  Synthesis and structural characterization of 1-(3-aminopropyl)silatrane and some new derivatives

  摘要：

  The research goal was to synthesize and structurally characterize a silatrane intended to be subsequently incorporated into metal complex structures. 3-Aminopropyltrialkoxysilane was reacted with triethanolamine in 1:1 molar ratio, either in bulk, in the presence of metallic sodium, or in a solvent mixture. 1-(3-Aminopropyl)silatrane in carbamate form or having free amine groups was obtained. The latter was reacted with 2-hydroxybenzaldehyde, 2,4-dihydroxybenzaldehyde and CoCl2 or with CoCl2 only. The crystalline reaction products were characterized by elemental and spectral (FTIR and H-1 NMR) analyses and single crystal X-ray diffractometry, which revealed the formation of new, either sought (1-(3-aminopropyl)silatrane, 1-(3-salicyliminopropyl)silatrane) or unexpected (N-carboxylated 1-(3-aminopropyl)silatrane and 1-chlorocobaltrane) structures. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.014