[Zn2Nd(N,N'-bis(salicylidene)phenylene-1,2-diamine(-2H))(NO3)3(MeCN)2] | 1266138-19-5

• 英文名称: [Zn2Nd(N,N'-bis(salicylidene)phenylene-1,2-diamine(-2H))(NO3)3(MeCN)2]
• CAS: 1266138-19-5
• 化学式: C₄₄H₃₄N₉NdO₁₃Zn₂
• 分子量: 1171.83
• InChiKey: LNHTVWWPIXYZRU-RJFXVBMZSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  neodymium(III) nitrate hexahydrate 、 [Zn(N,N'-bis(salicylidene)phenylene-1,2-diamine(-2H))(MeCN)] 、 乙腈 以 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 生成 [Zn2Nd(N,N'-bis(salicylidene)phenylene-1,2-diamine(-2H))(NO3)3(MeCN)2]
  参考文献：
  名称：

  Anion-induced near-infrared (NIR) luminescent Zn2Nd and ZnNd complexes based on the pure Salen-type Schiff-base ligand

  摘要：

  With the Zn-Schiff-base [ZnL(CH3CN)] from the pure Salen-type Schiff-base ligand H2L (H2L = N,N'-bis (salicylidene)phenylene-1,2-diamine) as the precursor, a hetero-trinuclear Zn2Nd complex [Zn2Nd(L)(2)(NO3)(3)(CH3CN)(2)] (1) and a hetero-binuclear ZnNd complex [ZnNd(L)(2)Cl(DMF)] (2) are obtained by the further reaction with Nd(NO3)(3)center dot 6H(2)O or NdCl3 center dot 6H(2)O, respectively. The influence of structural differences of the two complexes on their photophysical properties shows the anionic inducement leads to the effective modulation of the NIR luminescent properties by the adjustment of the coordination sphere of the Nd3+ ions. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.09.035