1,1'-bis(mesitylthio)ferrocene | 305866-41-5

• 英文名称: 1,1'-bis(mesitylthio)ferrocene
• CAS: 305866-41-5
• 化学式: C₂₈H₃₀FeS₂
• 分子量: 486.525
• InChiKey: AETHVPUOOLLMQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(benzonitrile)dichloroplatinum(II) 、 1,1'-bis(mesitylthio)ferrocene 以 甲苯 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Hang-gliding with Ferrocenes:  Unusual Coordination Chemistry of 1,1‘-Bis(mesitylthio)ferrocene

  摘要：

  A rare C,S-cyclometalated Pt-IV complex is one of a series of transition metal complexes formed by the new redox-active and sterically hindered ligand 1,1'-bis(mesitylthio)ferrocene. Simple Pd-II and Pt-II chelate species can be synthesized by less forcing reaction conditions, in addition to a Re-2(CO)(6)Br-2 dinuclear species featuring the ferrocene ligand adopting a binucleating role and forming an unusual "quasi-closed" bridged structure.

  DOI：

  10.1021/om0004388
• 作为产物：
  描述：

  1,1′-dilithioferrocene 、 bis(2,4,6-trimethylphenyl)disulfide 以 正己烷 、 甲苯 为溶剂， 以65%的产率得到1,1'-bis(mesitylthio)ferrocene
  参考文献：
  名称：

  Hang-gliding with Ferrocenes:  Unusual Coordination Chemistry of 1,1‘-Bis(mesitylthio)ferrocene

  摘要：

  A rare C,S-cyclometalated Pt-IV complex is one of a series of transition metal complexes formed by the new redox-active and sterically hindered ligand 1,1'-bis(mesitylthio)ferrocene. Simple Pd-II and Pt-II chelate species can be synthesized by less forcing reaction conditions, in addition to a Re-2(CO)(6)Br-2 dinuclear species featuring the ferrocene ligand adopting a binucleating role and forming an unusual "quasi-closed" bridged structure.

  DOI：

  10.1021/om0004388