[Re(bipy)(CO)₃(SMe₂)](OTf) | 1438417-05-0

• 英文名称: [Re(bipy)(CO)₃(SMe₂)](OTf)
• CAS: 1438417-05-0
• 化学式: CF₃O₃S*C₁₅H₁₄N₂O₃ReS
• 分子量: 637.631
• InChiKey: NHNXXWXJMFLADP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Re(bipy)(CO)₃(SMe₂)](OTf) 在 双(三甲基硅烷基)氨基钾 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 以37.888%的产率得到
  参考文献：
  名称：

  Intramolecular Nucleophilic Addition to the 2 Position of Coordinated 2,2′-Bipyridine by a Deprotonated Dimethyl Sulfide Ligand

  摘要：

  Deprotonation of the dimethyl sulfide ligand in [Re(bipy)(CO)(3)(SMe2)][OTf] (1) by KN(SiMe3)(2) afforded a mixture of two diastereomers (2M and 2m) in which a C-C bond has been formed between the S-bonded CH2 group and the 2 position of 2,2'-bipyridine. The solid-state structure of the more stable 2,6-Pr-i-BIAN analogue could be determined by X-ray diffraction.

  DOI：

  10.1021/ic401065h
• 作为产物：
  描述：

  (2,2'-bipyridine)tricarbonylrhenium trifluoromethanesulfonate 、 二甲基硫 以 二氯甲烷 为溶剂， 反应 6.0h， 以91.4%的产率得到[Re(bipy)(CO)₃(SMe₂)](OTf)
  参考文献：
  名称：

  Intramolecular Nucleophilic Addition to the 2 Position of Coordinated 2,2′-Bipyridine by a Deprotonated Dimethyl Sulfide Ligand

  摘要：

  Deprotonation of the dimethyl sulfide ligand in [Re(bipy)(CO)(3)(SMe2)][OTf] (1) by KN(SiMe3)(2) afforded a mixture of two diastereomers (2M and 2m) in which a C-C bond has been formed between the S-bonded CH2 group and the 2 position of 2,2'-bipyridine. The solid-state structure of the more stable 2,6-Pr-i-BIAN analogue could be determined by X-ray diffraction.

  DOI：

  10.1021/ic401065h