(di(2-pyridyl)methanesulfonate)Pt(II)(C2H4NH2CH3)Cl | 1307300-09-9

• 英文名称: (di(2-pyridyl)methanesulfonate)Pt(II)(C2H4NH2CH3)Cl
• CAS: 1307300-09-9
• 化学式: C₁₄H₁₈ClN₃O₃PtS
• 分子量: 538.914
• InChiKey: MKWWKSAIRMCHHO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (di(2-pyridyl)methanesulfonate)Pt(II)(C2H4NH2CH3)Cl 以 氘代二甲亚砜 为溶剂， 生成 (di(2-pyridyl)methanesulfonate)Pt(II)(dmso-d6)Cl
  参考文献：
  名称：

  Stoichiometric aerobic aminohydroxylation of ethylene mediated by dpms–platinum complexes (dmps=di(2-pyridyl)methanesulfonate)

  摘要：

  Chloro di(2-pyridyl) methanesulfonate ethylene platinum(II) complex was converted to corresponding N-alkylplatina(II)azetidines by reacting the former with primary amines, MeNH(2) and tert-BuNH(2), to produce 2-ammonioethyl chloro platinum(II) species and their subsequent cyclization in the presence of NaOH in methanol. The N-alkylplatina(II) azetidines are oxidized under air or the atmosphere of pure O(2) to the corresponding N-alkylplatina(IV) azetidines in water or in methanol solution in the presence of one equivalent of a strong acid under ambient pressure at 22 degrees C. The resultin N-alkylplatina(IV)azetidines undergo C-O reductive elimination in acidic aqueous solutions to produce 2-(N-alkylamino)ethanols. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.09.057
• 作为产物：
  描述：

  chloro di(2-pyridyl)methanesulfonate ethylene platinum(II) 、 甲胺 以 甲醇 为溶剂， 以90%的产率得到(di(2-pyridyl)methanesulfonate)Pt(II)(C2H4NH2CH3)Cl
  参考文献：
  名称：

  Stoichiometric aerobic aminohydroxylation of ethylene mediated by dpms–platinum complexes (dmps=di(2-pyridyl)methanesulfonate)

  摘要：

  Chloro di(2-pyridyl) methanesulfonate ethylene platinum(II) complex was converted to corresponding N-alkylplatina(II)azetidines by reacting the former with primary amines, MeNH(2) and tert-BuNH(2), to produce 2-ammonioethyl chloro platinum(II) species and their subsequent cyclization in the presence of NaOH in methanol. The N-alkylplatina(II) azetidines are oxidized under air or the atmosphere of pure O(2) to the corresponding N-alkylplatina(IV) azetidines in water or in methanol solution in the presence of one equivalent of a strong acid under ambient pressure at 22 degrees C. The resultin N-alkylplatina(IV)azetidines undergo C-O reductive elimination in acidic aqueous solutions to produce 2-(N-alkylamino)ethanols. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.09.057