dichloro(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II) | 622828-86-8

• 英文名称: dichloro(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II)
• CAS: 622828-86-8
• 化学式: C₁₆H₁₀Cl₂N₂PdS₄
• 分子量: 535.859
• InChiKey: ACJYGFYUNQXNDW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  4,5-双(苯甲酰硫基)-1,3-二硫杂环戊烯-2-硫酮 、 dichloro(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II) 在 methanate sodium 作用下， 以 甲醇 为溶剂， 以54%的产率得到(dmit)(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II)
  参考文献：
  名称：

  ‘Unsymmetric’ palladium(II) complexes with ligand 4′,5′-diaza-9′-(4,5-disubstituted-1,3-dithiole-2-ylidene)-fluorene

  摘要：

  Four 'unsyminetric' complexes of palladium(II), [Pd(L)Cl-2] and [Pd(L)(dmit)], have been synthesized and characterized [L = 4', 5'-diaza-9'-(4.5-bis(methylthio)-1,3-dithiole-2-ylidene)-fluorene (L-1) and 4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene (L-2)]. Single crystal Structure of [Pd(L-1)Cl-2] was determined, in which, the atoms of the molecule, except two methyl-groups, are conjugated in a quasi-plane. The planar molecules are further stacked forming two unequivalent columns with C...C, S...C and S...Cl contacts. The differences between dichloro complexes and dmit complexes in IR, UV and oxidation properties were discussed in detail. The dmit complexes exhibit LLCT hand from dmit (donor) to pi* of L-1 (acceptor). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00176-2
• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene 以 氯仿 为溶剂， 以81%的产率得到dichloro(4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene)palladium(II)
  参考文献：
  名称：

  ‘Unsymmetric’ palladium(II) complexes with ligand 4′,5′-diaza-9′-(4,5-disubstituted-1,3-dithiole-2-ylidene)-fluorene

  摘要：

  Four 'unsyminetric' complexes of palladium(II), [Pd(L)Cl-2] and [Pd(L)(dmit)], have been synthesized and characterized [L = 4', 5'-diaza-9'-(4.5-bis(methylthio)-1,3-dithiole-2-ylidene)-fluorene (L-1) and 4',5'-diaza-9'-(4,5-ethylenedithio-1,3-dithiole-2-ylidene)-fluorene (L-2)]. Single crystal Structure of [Pd(L-1)Cl-2] was determined, in which, the atoms of the molecule, except two methyl-groups, are conjugated in a quasi-plane. The planar molecules are further stacked forming two unequivalent columns with C...C, S...C and S...Cl contacts. The differences between dichloro complexes and dmit complexes in IR, UV and oxidation properties were discussed in detail. The dmit complexes exhibit LLCT hand from dmit (donor) to pi* of L-1 (acceptor). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00176-2