dicyclopentadienyl gadolinium chloride | 11087-14-2

• 英文名称: dicyclopentadienyl gadolinium chloride
• 英文别名: (η5-cyclopentadienyl)2 gadolinium(III)chloride；(cyclopentadienyl)2GdCl；Gd(η-C5H5)2Cl
• CAS: 11087-14-2
• 化学式: C₁₀H₁₀ClGd
• 分子量: 322.892
• InChiKey: PHIURGAKPFLDMP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dicyclopentadienyl gadolinium chloride 在 2,2'-联吡啶 作用下， 以 四氢呋喃 为溶剂， 以64%的产率得到dicyclopentadienyl gadolinium chloride 2,2'-bipyridyl complex
  参考文献：
  名称：

  Qian, Changtao; Yao, Beili; Huang, Saitang, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1984, vol. 14, p. 663 - 678

  摘要：

  DOI：

文献信息

• Synthesis and properties of new σ-bonded organolanthanide complexes and studies of their infrared spectra
  作者：Changtao Qian、Changqing Ye、Hanzhang Lu、Yuqin Li、Jialie Zhou、Yuanwen Ge、Minoru Tsutsui

  DOI：10.1016/s0022-328x(00)98751-5

  日期：1983.5

  by elemental analyses, infrared spectra and mass spectra. Recrystallization of these complexes from non-polar solvents such as benzene-n-hexane or toluene-n-hexane led to removal of coordinated tetrahydrofuran resulting in unsolvated products. The thermal decomposition temperature and the variable temperature (77–291 K) magnetic susceptibilities of the five unsolvated complexes were measured. The relation

  含LNCσ-键五个新的溶剂化金属有机配合物（η 5 -CH 3 Ç 5 ħ 4）2 ERC 6 ħ 4 CH 3 - p ·THF（I），（η 5 -C 5 H ^ 5）2 LNC 6 H 4 X- p ·THF，L n ＝ Er，X ＝ CH 3（II）；m / z 。Ln Er，XCl（III）；LnYb，X = CH 3（IV）；LN钆，XCH 3（V），通过适当的芳基锂衍生物与反应，合成（η 5 -C 5ħ 5）2 LnCl或（η 5 -CH 3 Ç 5 ħ 4）2 LnCl在THF中在低温（-78℃）。这些配合物的结构通过元素分析，红外光谱和质谱验证。这些配合物从非极性溶剂（如苯-正己烷或甲苯-正己烷）中重结晶导致除去配位的四氢呋喃，从而产生未溶剂化的产物。测量了五个未溶剂化配合物的热分解温度和可变磁化率（77-291 K）。还讨论了结构与氧化稳定性和热稳定性之间的关系。
• Selective O2 oxidation of air-sensitive lanthanocene thiolates and thioether chelate
  作者：Xigeng Zhou、Ming Zhu、Libei Zhang、Zhenyu Zhu、Chengfu Pi、Zhen Pang、Linhong Weng、Ruifang Cai

  DOI：10.1039/b417609j

  日期：——

  Two unusual regioselective O2 oxidation reactions of air-sensitive lanthanocene thiolates and a thioether chelate are described, revealing a novel oxygenation pattern of thiolate ligands.

  空气敏感的镧系茂硫醇盐和硫醚螯合物的两个不寻常的区域选择性O2氧化反应进行了描述，揭示了硫醇盐配体的新型氧化模式。
• Qian, Changtao; Ye, Changqing; Lu, Hanzhang, Inorganica Chimica Acta, 1984, vol. 94, p. 52 - 53
  作者：Qian, Changtao、Ye, Changqing、Lu, Hanzhang、Li, Yuqin、Zhou, Jialie、Ge, Yuanwen

  DOI：——

  日期：——
• Insertion of Carbodiimide into the Ln−C σ-Bond of Organolanthanide Complexes. Synthesis, Reaction, and Characterization of Organolanthanide Amidinates (C₅H₅)₂Ln[<i>^t</i>BuNC(<i>ⁿ</i>Bu)N<i>^t</i>Bu] (Ln = Er, Gd, Y)
  作者：Jie Zhang、Ruan、Shao、Cai、Weng、Zhou

  DOI：10.1021/om0109859

  日期：2002.4.1

  The synthesis, structures, and reactivity of new lanthanocene complexes incorporating amidinate ligand [(BuN)-Bu-t - C(Bu-n) - (NBu)-Bu-t] are described. Treatment of Cp(2)Ln(n)Bu (Ln = Er (1), Y (2), Gd (3)) with N,N-di-tert-butylcarbodiimide results in monoinsertion of carbodiimide into the Ln-C sigma-bond to yield the title compounds Cp(2)Ln[(BuN)-Bu-t-C(Bu-n) - (NBu)-Bu-t] (Ln = Er (4), Y (5), Gd (6)). Complexes 4-6 were characterized by elemental analysis and IR and mass spectroscopies. The structures of complexes 4 and 5 were determined through X-ray single-crystal diffraction analysis. It is shown that compound 5 is a fine catalyst for cyclotrimerization of phenyl isocyanate.
• A Lanthanide−Gallium Complex Stabilized by the N-Heterocyclic Carbene Group
  作者：Polly L. Arnold、Stephen T. Liddle、Jonathan McMaster、Cameron Jones、David P. Mills

  DOI：10.1021/ja0710858

  日期：2007.5.1

  The complex [Nd(L')Ga(NArCH)(2)}(N' ')(THF)], which exhibits the first f-element-gallium bond, is formed from the reaction between the N-heterocyclic carbene-supported neodymium complex [Nd(L')(N' ')(I)] (L' = (BuNCH2CH2)-N-tC(NCSiMe3 CHNBut)}; N' ' = N(SiMe3)(2)) and the anionic gallium(I) heterocycle [Ga(NArCH)(2)][K(tmeda)] (Ar = 2,6-(Pr2C6H3)-C-i). The Nd-Ga bond energy is calculated to be 386 kJ mol(-1).