| 910130-72-2

• CAS: 910130-72-2
• 化学式: C₂₅H₁₅AuClN
• 分子量: 561.82
• InChiKey: FDNZQGKMSVKZES-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 copper(l) iodide 作用下， 以 二氯甲烷 为溶剂， 反应 9.5h， 生成
  参考文献：
  名称：

  铂（II）和金（III）亚烯基配合物：磷光，自组装的纳米结构和细胞毒性

  摘要：

  三重双键的亮面：发现两个系列的稳定的三齿环金属化的Pt II和Au III亚烯基配合物表现出许多功能，例如长寿命的激发态，自组装成超分子纳米结构，DNA和细胞核结合以及细胞成像功能（见图）。

  DOI：

  10.1002/chem.201301481

文献信息

• Strongly Luminescent Gold(III) Complexes with Long-Lived Excited States: High Emission Quantum Yields, Energy Up-Conversion, and Nonlinear Optical Properties
  作者：Wai-Pong To、Kaai Tung Chan、Glenna So Ming Tong、Chensheng Ma、Wai-Ming Kwok、Xiangguo Guan、Kam-Hung Low、Chi-Ming Che

  DOI：10.1002/anie.201301149

  日期：2013.6.24

  Photochemistry: A series of emissive gold(III) complexes with fluorene‐containing cyclometalating ligands exhibits strong phosphorescence and long‐lived excited states with emission quantum yields and lifetimes up to 58 % and 305 μs, respectively. These complexes can sensitize energy up‐conversion of 9,10‐diphenylanthracene (DPA; see picture) and display rich two‐photon absorption properties (TPA; TTA=triplet–triplet

  光化学：具有含芴的环金属化配体的一系列发光金（III）配合物表现出强磷光和长寿命激发态，其发射量子产率和寿命分别高达58％和305μs。这些配合物可以使9,10-二苯基蒽（DPA；参见图片）的能量上转换敏感，并显示出丰富的两光子吸收特性（TPA； TTA =三重态-三重态an灭）。
• Functionalized Bis-Cyclometalated Alkynylgold(III) Complexes: Synthesis, Characterization, Electrochemistry, Photophysics, Photochemistry, and Electroluminescence Studies
  作者：Vonika Ka-Man Au、Daniel Ping-Kuen Tsang、Keith Man-Chung Wong、Mei-Yee Chan、Nianyong Zhu、Vivian Wing-Wah Yam

  DOI：10.1021/ic4019212

  日期：2013.11.4

  A series of luminescent alkynylgold(III) complexes containing various tridentate bis-cyclometalating ligands derived from 2,6-diphenylpyridine (R-(CNC)-N-boolean AND-C-boolean AND), [Au(R-(CNC)-N-boolean AND-C-boolean AND)(C C-C6H4-R'] has been successfully synthesized and characterized. Complexes 1 and 6 have been determined by X-ray crystallography. Electrochemical studies show a ligand-centered reduction that originated from the tridentate R-(CNC)-N-boolean AND-C-boolean AND pincer ligands and an alkynyl-centered oxidation. The photophysical properties of the complexes have been studied in detail by electronic absorption and emission studies. Tunable photoluminescence behaviors have been observed, with the emission maxima spanning through the visible region from 476 to 669 nm in dichloromethane at room temperature, and the complexes were also found to be emissive in various media at both room and low temperatures. Transient absorption studies have been conducted to investigate the excited state properties of the complexes. Furthermore, selected complexes have been incorporated into the emissive layer (EML) of organic light-emitting devices (OLEDs) and have demonstrated interesting electroluminescence.
• Luminescent Metallogels of Bis-Cyclometalated Alkynylgold(III) Complexes
  作者：Vonika Ka-Man Au、Nianyong Zhu、Vivian Wing-Wah Yam

  DOI：10.1021/ic3007519

  日期：2013.1.18

  A series of luminescent bis-cyclometalated alkynylgold(III) complexes have been synthesized and characterized. Some of the complexes have been demonstrated to exhibit gelation properties driven by pi-pi stacking and hydrophobic-hydrophobic interactions. The gelation properties have been investigated in detail through variable-temperature UV-vis absorption and emission studies, and the morphology of the gels has also been characterized by scanning electron microscopy and transmission electron microscopy.