trans(benzothiadiazole-N)carbonylchlorohydridobis(triphenylphosphine)ruthenium(II) | 128817-71-0

• 英文名称: trans(benzothiadiazole-N)carbonylchlorohydridobis(triphenylphosphine)ruthenium(II)
• 英文别名: [RuHCl(CO)(2,1,3-benzothiadiazole)(PPh3)2]；[RuHCl(CO)(2,1,3-benzothiadiazole)(PPh₃)₂]
• CAS: 128817-71-0
• 化学式: C₄₃H₃₅ClN₂OP₂RuS
• 分子量: 826.3
• InChiKey: SYVZKYSWTVXEFP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans(benzothiadiazole-N)carbonylchlorohydridobis(triphenylphosphine)ruthenium(II) 、 邻羟苯亚甲基邻溴苯胺 在 NaOCH₃ 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 以53%的产率得到
  参考文献：
  名称：

  Ruthenium hydride and vinyl complexes supported by nitrogen–oxygen mixed-donor ligands

  摘要：

  The Schiff base, 2-chlorophenylsalicylaldimine (HL1), is formed readily from salicylaldehyde and 2-chloroaniline. After deprotonation, this ligand is found to react as a bidentate mixed-donor chelate with the complexes [RuRCl(CO)(BTD)(PPh3)(2)] (R = H, CH=CHC6H5, CH=CHC6H4Me-4, CH=CH'Bu, CC CPh=CHPh; BTD = 2,1,3-benzothiadiazole) to form the compounds [RuR(L-1)(CO)(PPh3)(2)] through displacement of the chloride and BTD ligands. An analogous reaction occurs with the osmium complex [OsHCl(CO)(BTD)(PPh3)(2)] to provide [OsH(L-1)(CO)(PPh3)(2)]. The compound [Ru(CH=CHC6H4Me-4)(L-1)(CO)(PPh3)(2)] is formed through reaction of salicylalclehyde (HL2) with [Ru(CH=CHC6H4Me-4)Cl(CO)(BTD)(PPh3)(2)] in the presence of base. Two further ligands were investigated to extend the study to encompass 5- and 4-membered chelates; 8-hydroxyquinoline (HL3) and 2-hydroxy-4-methylquinoline (HL4) react with [Ru(CH=CHPh)Cl(CO)(BTD)(PPh3)(2)] and [Ru(CH=CHC6H4Me-4)Cl(CO)(BTD)(PPh3)(2)] in the presence of base to yield the complexes [Ru(CH=CHPh)(L-3)(CO)(PPh3)(2)] and [Ru (CH=CHC6H4Me-4)(L-4)(CO)(PPh3)(2)], respectively. The crystal structure of [Ru(CH=CHC6H4Me-4)(L-1)(CO)(PPh3)(2)] is reported. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.04.036
• 作为产物：
  描述：

  2,1,3-苯并噻二唑 、 [RuHCl(CO)(PPh₃)₃] 以 四氢呋喃 为溶剂， 以80%的产率得到trans(benzothiadiazole-N)carbonylchlorohydridobis(triphenylphosphine)ruthenium(II)
  参考文献：
  名称：

  笔记。钌的水合（苯并硫代二唑）配合物：[RuCl（H）（CO）（PPh 3）（SN 2 C 6 H 4）]的晶体结构

  摘要：

  络合物[RuCl（H）（CO）（PPh 3）3 ]与2,1,3-苯并噻二唑（C 6 H 4 N 2 S）或2,1,3-苯并硒二唑（C 6 H 4 N 2 Se ）以提供化合物[RuCl（H）（CO）（PPh 3）2（EN 2 C 6 H 4）]（E = S或Se）。反式-[RuCl（H）（CO）（PPh 3）2（SN 2 C 6 H 4）的X射线衍射研究）]建立了通过一个氮原子和顺式与氢配体配位的杂环配位方式。晶体结构还显示了不对称单元的两个分子的未配位的NS多重键之间的不寻常的四中心相互作用。

  DOI：

  10.1039/dt9900001737

文献信息

• The stepwise generation of multimetallic complexes based on a vinylbipyridine linkage and their photophysical properties
  作者：Anita Toscani、Khairil A. Jantan、Jubeda B. Hena、Jonathan A. Robson、Emily J. Parmenter、Valentina Fiorini、Andrew J. P. White、Stefano Stagni、James D. E. T. Wilton-Ely

  DOI：10.1039/c6dt03810g

  日期：——

  The versatile rhenium complex [ReCl(CO)3(bpyC[identical with]CH)] (HC[identical with]Cbpy = 5-ethynyl-2,2'-bipyridine) is used to generate a series of bimetallic complexes through the hydrometallation of [MHCl(CO)(BTD)(PPh3)2] (M = Ru, Os; BTD = 2,1,3-benzothiadiazole). The...

  通用rh络合物[ReCl（CO）3（bpyC [与CH]相同）（HC [与Cbpy = 5-乙炔基-2,2'-联吡啶））用于通过加氢金属化反应生成一系列双金属络合物[MHCl（CO）（BTD）（PPh3）2]的摩尔数（M = Ru，Os; BTD = 2,1,3-苯并噻二唑）。这...