1-(ethoxymethoxy)-2-allyl-1,2-dicarba-closo-dodecaborane | 199180-65-9

• 英文名称: 1-(ethoxymethoxy)-2-allyl-1,2-dicarba-closo-dodecaborane
• CAS: 199180-65-9
• 化学式: C₈H₂₂B₁₀O₂
• 分子量: 258.371
• InChiKey: WOBOJXQSYFMYSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 1-(ethoxymethoxy)-2-allyl-1,2-dicarba-closo-dodecaborane 在 9-BBN 、 NaOH 、 H₂O₂ 作用下， 以 四氢呋喃 为溶剂， 以98%的产率得到1-hydroxy-2-(3-hydroxypropyl)-1,2-dicarba-closo-dodecaborane
  参考文献：
  名称：

  C-Hydroxydicarba-closo-dodecaboranes

  摘要：

  An improved synthesis and a full characterization of all three 12-vertex C-hydroxydicarba-closo-dodecaboranes 1-3 are reported. These inorganic analogues of phenols are highly acidic, but unlike phenols, they are transparent in the near-UV region and are stable to oxidation. The structure of their oxyanions 1a-3a poses an interesting issue of a close versus a bridged nido form. Also described is an introduction of a functionalized spacer in position 2 of 1 designed to permit incorporation into more complex organic structures.

  DOI：

  10.1021/ic970796b
• 作为产物：
  描述：

  丙烯酰碘 、 1-hydroxy-1,2-dicarba-closo-dodecaborane 、 氯甲基乙醚 在 NaH 、 BuLi 作用下， 以 四氢呋喃 为溶剂， 以95%的产率得到1-(ethoxymethoxy)-2-allyl-1,2-dicarba-closo-dodecaborane
  参考文献：
  名称：

  C-Hydroxydicarba-closo-dodecaboranes

  摘要：

  An improved synthesis and a full characterization of all three 12-vertex C-hydroxydicarba-closo-dodecaboranes 1-3 are reported. These inorganic analogues of phenols are highly acidic, but unlike phenols, they are transparent in the near-UV region and are stable to oxidation. The structure of their oxyanions 1a-3a poses an interesting issue of a close versus a bridged nido form. Also described is an introduction of a functionalized spacer in position 2 of 1 designed to permit incorporation into more complex organic structures.

  DOI：

  10.1021/ic970796b