[Cu(bis(N,N'-(salicylidene)-2,2-dimethyl-1,3-propanediamine(2-))*Cu(N3)2*THF]2 | 534568-35-9

• 英文名称: [Cu(bis(N,N'-(salicylidene)-2,2-dimethyl-1,3-propanediamine(2-))*Cu(N3)2*THF]2
• 英文别名: bis[[(tetrahydrofuran)-μ-N,N'-bis(salicylidene)-2,2'-dimethyl-1,3-propanediaminatocopper(II)](azido)-(μ-azido-1:1)copper(II)]
• CAS: 534568-35-9
• 化学式: C₄₆H₅₆Cu₄N₁₆O₆
• 分子量: 1183.24
• InChiKey: DFFDVJSRWUXIIM-IADFFFJNSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 四氢呋喃 、 [2,2'-[2,2-dimethyl-1,3-propanediyl-bis(nitrilomethylidyne)]diphenolato-κ(4)N,N',O,O']copper(II) 、 sodium azide 以 四氢呋喃 、 甲醇 、 水 为溶剂， 生成 [Cu(bis(N,N'-(salicylidene)-2,2-dimethyl-1,3-propanediamine(2-))*Cu(N3)2*THF]2
  参考文献：
  名称：

  Synthesis and Crystal Structure of Linear Chain Homotetranuclear Complexes with N₃ ⁻

  摘要：

  Mononuclear copper(II) complexes, Cu(L) [N,N'-bis(salicylidene)-1,3-propanediaminato]copper(II), and Cu(LDM) [N,N'-bis(salicylidene)2,2'-dimethyl-1,3-propanediaminato]copper(II), were prepared from the ONNO type ligands N,N'-bis(salicylidene)-1,3-diaminopropane (H2L) and N,N'-bis(salicylidene)-2,2'-dimethyl-1,3-diaminopropane (H2LDM). These mononuclear complexes were transformed into tetranuclear complexes, [(S)Cu(L)Cu(N-3)(2)](2) and [(S)Cu(LDM)Cu(N-3)(2)](2) (S are solvent molecules, DMSO, DMF, THF, dioxan), with N-3(-) and Cu(II) ions. All complexes were characterized by elemental analyses and IR spectroscopy. A molecular model of the complex [(DMSO)Cu(L)Cu(N-3)(2)] was obtained by single crystal x-ray diffraction methods.

  DOI：

  10.1081/sim-120017787

文献信息

• Oez, S.; Kunduraci, M.; Kurtaran, R., Journal of Thermal Analysis and Calorimetry, 2010, vol. 101, p. 221 - 228
  作者：Oez, S.、Kunduraci, M.、Kurtaran, R.、Ergun, Ue.、Arici, C.、et al.

  DOI：——

  日期：——