Tris(2,6-diisopropylphenylimido) complexes of molybdenum: kinetic accessibility of the d<sup>0</sup>Mo(NR)<sub>3</sub>functional group
作者:Donald L. Morrison、David E. Wigley
DOI:10.1039/c39950000079
日期:——
The unprecedented tris(imido) complex of molybdenum, [Li(THF)4][Mo(NAr)3Cl](Ar = C6H3Pri2-2,6), is the kinetic product of the reaction between [Mo(NAr)2Cl2(THF)2] and 2 equiv. of LiNHAr in THF; [Li(THF)4][Mo(NAr)3Cl] and byproduct H2NAr react further to form the thermodynamic product [Mo(NAr)2(NHAr)2].
前所未有的钼的三(亚氨基)络合物[Li(THF)4 ] [Mo(NAr)3 Cl](Ar = C 6 H 3 Pr i 2 -2,6),是[[ Mo(NAr)2 Cl 2(THF)2 ]和2当量。LiNHAr的四氢呋喃溶液;[Li(THF)4 ] [Mo(NAr)3 Cl]与副产物H 2 NAr进一步反应形成热力学产物[Mo(NAr)2(NHAr)2 ]。