| 1453262-36-6

• CAS: 1453262-36-6
• 化学式: C₂₉H₄₀FeO₂Si
• 分子量: 504.568
• InChiKey: VBGMKJBQZMYVBU-PPLJNSMQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 甲基磺酰氯 、 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 1.5h， 以2.01 g的产率得到
  参考文献：
  名称：

  Synthesis of planar chiral ferrocenyl cyclopentadienyl chelate ligand precursors

  摘要：

  Two families of planar chiral ferrocenyl cyclopentadienyl chelate ligands for use in ansa-half sandwich metallocene complexes of catalytically active transition metals are described. The first family was derived in 4-5 steps from an enzymatic resolution of 1-iodo-2-(methylalcohol)ferrocene and possesses a cyclopentadiene derivative [Cp(H) = 1-indenyl, 2-indenyl or Ph4Cp(H)] directly attached to the ferrocene ring with an adjacent vicinal tether CH(2)Z donor group (Z = OH, OMe, NHMe, NMe2 or PPh2). The second family was derived from a chiral auxiliary approach and has the donor group (Z = PPh2 or NMe2) attached directly to the ferrocene ring with an adjacent tether vicinal CH2Cp(H) group [Cp(H) = Cp(H), fluorenyl, 1-indenyl, Me4Cp(H) or Ph4Cp(H)]. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2013.07.006
• 作为产物：
  描述：

  、 1-茚酮 在 正丁基锂 作用下， 以 乙醚 、 正己烷 、 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of planar chiral ferrocenyl cyclopentadienyl chelate ligand precursors

  摘要：

  Two families of planar chiral ferrocenyl cyclopentadienyl chelate ligands for use in ansa-half sandwich metallocene complexes of catalytically active transition metals are described. The first family was derived in 4-5 steps from an enzymatic resolution of 1-iodo-2-(methylalcohol)ferrocene and possesses a cyclopentadiene derivative [Cp(H) = 1-indenyl, 2-indenyl or Ph4Cp(H)] directly attached to the ferrocene ring with an adjacent vicinal tether CH(2)Z donor group (Z = OH, OMe, NHMe, NMe2 or PPh2). The second family was derived from a chiral auxiliary approach and has the donor group (Z = PPh2 or NMe2) attached directly to the ferrocene ring with an adjacent tether vicinal CH2Cp(H) group [Cp(H) = Cp(H), fluorenyl, 1-indenyl, Me4Cp(H) or Ph4Cp(H)]. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2013.07.006