| 1350324-53-6

• CAS: 1350324-53-6
• 化学式: C₈₈H₁₁₂Br₂N₂NiO₄P₂S₂
• 分子量: 1606.45
• InChiKey: TZHSXUWVPAPPNV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dibromo[1,2-bis(diphenylphosphino)ethane]nickel(II) 、 以 氘代四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Chain-Growth Polymerization of Unusual Anion-Radical Monomers Based on Naphthalene Diimide: A New Route to Well-Defined n-Type Conjugated Copolymers

  摘要：

  Strongly electron-deficient (n-type) main-chain g-conjugated polymers are commonly prepared via well-established step-growth polycondensation protocols which enable limited control over polymerization. Here we demonstrate that activated Zn and electron-deficient brominated thiophene-naphthalene diimide oligomers form anion-radical complexes instead of conventional Zn-organic derivatives. These highly unusual zinc complexes undergo Ni-catalyzed chain-growth polymerization leading to n-type conjugated polymers with controlled molecular weight, relatively narrow polydispersities, and specific end-functions.

  DOI：

  10.1021/ja208710x