[(Rh(1,5-cyclooctadiene))2(MoCl(diethyldithiocarbamate))2(μ3-S)4] | 219611-64-0

• 英文名称: [(Rh(1,5-cyclooctadiene))2(MoCl(diethyldithiocarbamate))2(μ3-S)4]
• CAS: 219611-64-0
• 化学式: C₂₆H₄₄Cl₂Mo₂N₂Rh₂S₈
• 分子量: 1109.77
• InChiKey: YWDPOSNQRLBIJQ-UTKALLHPSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 1,2-二(4-吡啶基)乙烯 、 [(Rh(1,5-cyclooctadiene))2(MoCl(diethyldithiocarbamate))2(μ3-S)4] 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以46%的产率得到[((Rh(1,5-cyclooctadiene))2(Mo(diethyldithiocarbamate))2(μ3-S)4)2(μ-trans-1,2-bis(4-pyridyl)ethylene)2][BF4]4
  参考文献：
  名称：

  Preparation and structures of the cluster dimers consisting of Rh2Mo2S4 single-cubane units connected by two bidentate N-donor ligands

  摘要：

  Reactions of a single-cubane cluster [{Rh(cod)}(2){MoCl(dtc)}(2)(mu(3)-S)(4)] (cod = 1,5-cyclooctadiene, dtc = diethyldithiocarbamate) with 1 equiv. of L (L = pyrazine, 4,4'-bipyridyl, trans-1,2-bis(4-pyridyl)ethylene) in the presence of 2 equiv. of AgBF(4) in CH(2)Cl(2) gave doubly bridged double-cubane clusters [{IRh(cod)}(2){Mo(dtc)}(2)(mu(3)-S)(4))(2)(mu-L)(2)][BF(4)](4), whose structures were determined by the single-crystal X-ray analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.01.021