monosilver(IX) tetrasulfide | 207401-21-6

• 英文名称: monosilver(IX) tetrasulfide
• CAS: 207401-21-6
• 化学式: AgS₄
• 分子量: 236.132
• InChiKey: IHLBRQNFZUBZDO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.59
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  monosilver(IX) tetrasulfide 以 neat (no solvent) 为溶剂， 生成 银
  参考文献：
  名称：

  Study of Reactions of Silver and Sulfur Clusters

  摘要：

  The reactions between silver and sulfur clusters are studied with a laser double ablation reactor. The main reaction products are [AgS4](+), [AgS8](+), [AgS12](+), and [AgS16](+), which have different compositions from those of Ag/S clusters produced from Ag/S mixed sample by laser ablation. The photolysis of the products with a 193 nm excimer laser indicates that [AgS12](+) and [AgS16](+) have a photodissociation efficiency much higher than that of [AgS4](+) and [AgS8](+). The structure of the products and the mechanism of the reactions to form products [AgS12](+) and [AgS16](+) are discussed.

  DOI：

  10.1021/jp984560k
• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 monosilver(IX) tetrasulfide
  参考文献：
  名称：

  Study of Reactions of Silver and Sulfur Clusters

  摘要：

  The reactions between silver and sulfur clusters are studied with a laser double ablation reactor. The main reaction products are [AgS4](+), [AgS8](+), [AgS12](+), and [AgS16](+), which have different compositions from those of Ag/S clusters produced from Ag/S mixed sample by laser ablation. The photolysis of the products with a 193 nm excimer laser indicates that [AgS12](+) and [AgS16](+) have a photodissociation efficiency much higher than that of [AgS4](+) and [AgS8](+). The structure of the products and the mechanism of the reactions to form products [AgS12](+) and [AgS16](+) are discussed.

  DOI：

  10.1021/jp984560k