| 34745-01-2

• CAS: 34745-01-2；35978-44-0
• 化学式: C₂₁H₂₀BrNiOPS₂
• 分子量: 522.089
• InChiKey: RMVSAMGWMKUBSX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dibromobis(triphenylphosphine)nickel(II) 、 nickel(II) bis(ethylxanthate) 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Ethylxanthates and isopropylxanthates of nickel with triphenylphosphine as mixed π-acceptor ligand

  摘要：

  Nickel(II)xanthates with triphenylphosphine as mixed pi-acceptor ligand of the composition [NiX(RXa)(PPh(3))] (X = Cl, Pr, I, NCS; R = Et, i-Pr; Xa = S2CO- have been prepared. All of these complexes have been characterized by elemental analysis, infrared and electronic absorption spectroscopy, magnetochemical measurements, thermal analysis and conductivity measurements. The [NiI(RXa)(PPh(3))] complexes have been one-electron irreversibly oxidized which was determined by cyclic voltammetry. A distorted square-planar arrangement of the coordination sphere with chromophore NiS2ClP has been proved by the X-ray structural analysis of the model [NiCl(i-PrXa)(PPh(3))] complex.

  DOI：

  10.1016/0277-5387(94)00433-f