(2,6-bis[4′,4′-dimethyloxazolin-2′-yl]pyridine)NiCl₂ | 1574527-26-6

• 英文名称: (2,6-bis[4′,4′-dimethyloxazolin-2′-yl]pyridine)NiCl₂
• 英文别名: (Dm-Pybox)NiCl₂
• CAS: 1574527-26-6
• 化学式: C₁₅H₁₉Cl₂N₃NiO₂
• 分子量: 402.931
• InChiKey: CIXYDXHMTFLCGG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 (2,6-bis[4′,4′-dimethyloxazolin-2′-yl]pyridine)NiCl₂ 生成
  参考文献：
  名称：

  Preparation, structures, and properties of nickel complexes containing 2,6-bis[4′,4′-dimethyloxazolin-2′-yl]pyridine, a pincer ligand

  摘要：

  Five- and six-coordinate nickel complexes [(Dm-Pybox)NiCl2], [(Dm-Pybox)Ni(H2O)Cl-2], [(Dm-Pybox)Ni(H2O)(2)Cl]Cl (2a), and [(Dm-Pybox)Ni(MeOH)(2)Cl]Cl (2b), where Dm-Pybox is 2,6-bis[4,4-dimethyloxazolin-2-yl]pyridine, have been isolated and structurally characterized by single crystal X-ray diffraction. The solid state structures of 2a and 2b feature different modes of non-covalent interactions, C-HCl, C-HO and O-HCl interactions. Spectroscopic and analytical methods, UV-vis and thermogravimetric analyses were done to further investigate chemical properties of the complexes.

  DOI：

  10.1080/00958972.2014.886109
• 作为产物：
  描述：

  bis(triphenylphosphine)nickel(II) chloride 、 2,6-bis[4',4'-dimethyloxazolin-2'-yl]pyridine 以 二氯甲烷 为溶剂， 以74%的产率得到(2,6-bis[4′,4′-dimethyloxazolin-2′-yl]pyridine)NiCl₂
  参考文献：
  名称：

  Preparation, structures, and properties of nickel complexes containing 2,6-bis[4′,4′-dimethyloxazolin-2′-yl]pyridine, a pincer ligand

  摘要：

  Five- and six-coordinate nickel complexes [(Dm-Pybox)NiCl2], [(Dm-Pybox)Ni(H2O)Cl-2], [(Dm-Pybox)Ni(H2O)(2)Cl]Cl (2a), and [(Dm-Pybox)Ni(MeOH)(2)Cl]Cl (2b), where Dm-Pybox is 2,6-bis[4,4-dimethyloxazolin-2-yl]pyridine, have been isolated and structurally characterized by single crystal X-ray diffraction. The solid state structures of 2a and 2b feature different modes of non-covalent interactions, C-HCl, C-HO and O-HCl interactions. Spectroscopic and analytical methods, UV-vis and thermogravimetric analyses were done to further investigate chemical properties of the complexes.

  DOI：

  10.1080/00958972.2014.886109