(η5-cyclopentadienyl)diiodo(Me3phosphine)molybdenum | 123934-33-8

• 英文名称: (η5-cyclopentadienyl)diiodo(Me3phosphine)molybdenum
• CAS: 123934-33-8
• 化学式: C₁₁H₂₃I₂MoP₂
• 分子量: 567.0
• InChiKey: SBDKOHWRUPNFJO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (η5-cyclopentadienyl)diiodo(Me3phosphine)molybdenum 在 碘 作用下， 以 二氯甲烷 为溶剂， 以68%的产率得到{(C₅H₅)MoI₂(P(CH₃)3)2}⁽¹⁺⁾*I₃^(1-)={(C₅H₅)MoI₂(P(CH₃)3)2}I₃
  参考文献：
  名称：

  The first electron transfer chain catalyzed ligand substitution reaction that occurs by transforming an odd-electron system into an even-electron one

  摘要：

  The substitution of I- by Cl- in CpMoI2(PMe3)2 to afford CpMoCl2(PMe3)2 is catalyzed by 1-electron oxidation, which produces the paramagnetic 16-electron [CpMoI2(PMe3)2]+ complex. Halide substitution is more rapid on the 16-electron cationic complex than on the 17-electron neutral one to produce [CpMoCl2(PMe3)2]+, and an endoergic electron transfer step follows to close a catalytic cycle with constitutes the first reported electron transfer chain catalytic pathway in ligand substitution where exchange is made faster by going from an odd- to an even-electron system. The efficiency of the catalysis is low because of the endoergic electron transfer and because the 16-electron dichloride cation is decomposed by excess chloride. The [CpMoI2(PMe3)2]+ complex has been isolated in salts with the PF6-, I3-, and I- counterions. The interaction between CpMoI2(PMe3)2 and I2 in a 2:1 molar ratio shows that, after rapid formation of the [CpMoI2(PMe3)2]+I- salt, slow disproportionation occurs with formation of CpMoI2(PMe3)2 and [CpMoI2(PMe3)2]+I3-. The interaction between [CpMoCl2(PMe3)2]+ and Cl- has been investigated by NMR and cyclic voltammetry, which indicate the formation of the 18-electron CpMoCl3(PMe3)2, in equilibrium with the paramagnetic 16-electron CpMoC13(PMe3). The same equilibrium mixture has also been obtained from CpMoC12(PMe3)2 and PhI-Cl2 in a 2:1 molar ratio.

  DOI：

  10.1021/ja00030a027
• 作为产物：
  描述：

  环戊二烯铊 、 mer-MoI3(PMe3)3 以 四氢呋喃 为溶剂， 以33%的产率得到(η5-cyclopentadienyl)diiodo(Me3phosphine)molybdenum
  参考文献：
  名称：

  Krueger, Steven T.; Poli, Rinaldo; Rheingold, Arnold L., Inorganic Chemistry, 1989, vol. 28, # 26, p. 4599 - 4607

  摘要：

  DOI：

文献信息

• Poli, Rinaldo; Owens, Beth E.; Linck, Robert G., Inorganic Chemistry, 1992, vol. 31, # 4, p. 662 - 667
  作者：Poli, Rinaldo、Owens, Beth E.、Linck, Robert G.

  DOI：——

  日期：——
• Linck, Robert G.; Owens, Beth E.; Poli, Rinaldo, Gazzetta Chimica Italiana, 1991, vol. 121, # 3, p. 163 - 168
  作者：Linck, Robert G.、Owens, Beth E.、Poli, Rinaldo、Rheingold, Arnold L.

  DOI：——

  日期：——