fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)hydridomanganese(I) | 148447-53-4

• 英文名称: fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)hydridomanganese(I)
• 英文别名: fac-(CO)3(1,3-bis(diphenylphosphino)propane)MnH；fac-Mn(CO)3(1,2-bis(diphenylphosphino)propane)H；fac-Mn(CO)3(1,3-bis(diphenylphosphino)propane)H；fac-(CO)3(Ph2P(CH2)3PPh2)MnH；fac-[MnH(1,3-bis(diphenylphosphino)propane)(CO)3]；fac-[MnH(dppp)(CO)3]
• CAS: 148447-53-4
• 化学式: C₃₀H₂₇MnO₃P₂
• 分子量: 552.428
• InChiKey: CBCOUIBFUFRLQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)hydridomanganese(I) 、 氢溴酸 以 二氯甲烷 为溶剂， 生成 fac-Mn(CO)3(1,3-bis(diphenylphosphino)propane)Br
  参考文献：
  名称：

  fac-（CO）3（PP）Mn-Z配合物的制备，反应和红外光谱（PP = DEPE，DPPE，DPPP; Z = H，OTs，OMe，OC（O）OMe，NCO，Cl，Br， N 3）

  摘要：

  一系列新的八面体Mn（I）配合物fac-（CO）3（depe）Mn-Z（depe = 1,2-双（二乙基膦基）乙烷，Z = H，OTs，OMe，OC（O）OMe，NCO ，Cl，Br，N 3）已经被制备和表征，特别是关于它们的红外光谱。与配位的一氧化碳有关的羰基拉伸频率中观察到的变化是Z基团的函数。这些光谱与类似的dppp，1，3-双（二苯基膦基）丙烷和dppe，1，2-双（二苯基膦基）乙烷络合物的相似光谱的比较显示了用苯基取代磷原子上的乙基的效果。Depe叠氮基络合物（Z = N 3）与炔烃反应生成三唑并合物，在与HCl水解后释放出三唑并再生生成叠氮基的氯配合物。

  DOI：

  10.1016/s0022-328x(97)00043-0
• 作为产物：
  描述：

  以 氘代苯 为溶剂， 生成 fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)hydridomanganese(I)
  参考文献：
  名称：

  The synthesis and reactions of Mn and Re formyl complexes, fac-(PP)M(CO)3CHO. The X-ray structure of fac-(dppp)Mn(CO)3CH2OCH3

  摘要：

  Treatment of the salts fac-[(P-P)M(CO)4][BF4] (M = Mn, Re; P-P = dppe, dppp) with NaBH4 gives the corresponding formyl complexes, fac-(P-P)M(CO)3CHO in excellent yield. Solutions of these formyls undergo spontaneous loss of CO to give the corresponding hydrides, fac-(P-P)M(CO)3H. On treatment with methyl triflate or protic acids the formyls undergo expected disproportionation reactions; the X-ray crystal structure determination of one of the products, fac-(dppp)Mn(CO)3CH2OCH3, is reported.

  DOI：

  10.1016/0022-328x(94)88015-8

文献信息

• Reactions of dirhenium heptoxide with manganese(I) and rhenium(I) hydrido, alkoxo, methylcarbonato, carbonato-bridged, and methoxymethyl complexes. The X-ray structures of fac-(CO)3(dppp)MnOReO3 and fac-(CO)3(dppp)ReOReO3
  作者：Damon A. Brown、David M. Kimari、Anna M. Duzs-Moore、Theodore A. Budzichowski、Douglas M. Ho、Santosh K. Mandal

  DOI：10.1016/s0022-328x(02)01632-7

  日期：2002.9

  manganese(I) and rhenium(I) hydrido fac-(CO)3(PP)MH}, alkoxo fac-(CO)3(PP)MOR}, methylcarbonato fac-(CO)3(PP)MOC(O)OCH3}, carbonato-bridged [(CO)3(PP)M]2μ-OC(O)O} and methoxymethyl fac-(CO)3(PP)MCH2OCH3} complexes, where, R is CH3 or CH2CH3, PP is dppe 1,2-bis(diphenylphosphino)ethane} or dppp 1,3-bis(diphenylphosphino)propane}, yielded the corresponding perrhenato complexes, fac-(CO)3(PP)MOReO3

  再处理2 ö 7与锰（I）和铼（I）氢基 FAC - （CO）3，烷氧（PP）MH} FAC - （CO）3（PP）MOR}，methylcarbonato FAc-（CO）3（PP）MOC（O）OCH 3 }，羰基桥接的[（CO）3（PP）M] 2 μ-OC（O）O}和甲氧基甲基 FAc-（ CO）3（PP）MCH 2 OCH 3 }配合物，其中R为CH 3或CH 2 CH 3，PP为dppe 1,2-双（二苯基膦基）乙烷}或dppp 1,3-双（二苯基膦基）丙烷}，生成相应的perrhenato配合物FAc-（CO）3（PP）MOReO 3（1，M = Mn，PP= dppe; 2，M = Mn，PP= dppp; 3，M = Re，PP= dppe; 4，M = Re，PP= dppp），中等至极高的产量。所述perrhenato络合物已经光谱表征和的分子结构FAC
• Synthesis and X-ray structures of manganese(I) and rhenium(I) formato complexes, fac-(CO)3(dppp)MOC(H)O
  作者：Miyoshia T Williams、Christopher McEachin、Thomas M Becker、Douglas M Ho、Santosh K Mandal

  DOI：10.1016/s0022-328x(99)00743-3

  日期：2000.4

  The mononuclear manganese(I) and rhenium(I) formato complexes, fac-(CO)3(dppp)MOC(H)O (M=Mn, 1; M=Re, 2), have been prepared from fac-(CO)3(dppp)MH and formic acid, and their X-ray structures determined. Compounds 1 and 2 are unusual in that the formato ligands are bound in a terminal, monodentate fashion. For Mn, only multinuclear complexes containing bridging formato ligands have been characterized

  的单核锰（I）和铼（I）formato络合物，FAC - （CO）3（DPPP）MOC（H）O（M =锰1 ; M = RE，2），已经从制备FAC - （CO）3（DPPP）MH和甲酸，并确定其X射线结构。化合物1和2的不同之处在于，甲酰配体以末端单齿方式结合。对于Mn，先前仅通过X射线衍射表征了含有桥联甲酰基配体的多核络合物。所述MO键长和键MOC角度是2.043（2）和124.2（2）°，分别为1和2.167（3）和122.3（3）°，分别为2。化合物1和2也可以在高温下脱羧，同时定量回收FAc-（CO）3（DPPP）MH。
• One-pot synthesis of fac-[Mn(CO)3(PP)Cl] from Mn2(CO)10, [PP] and chlorinated solvents: [PP] = 1,2-bis(diethylphosphino)ethane (depe), 1,2-bis(diphenylphosphino)ethane (dppe) or 1,3-bis(diphenylphosphino)propane (dppp). The X-ray crystal structure of fac-[Mn(CO)3(depe)Cl]
  作者：Guang Qing Li、Julian Feldman、Jeanette A. Krause、Milton Orchin

  DOI：10.1016/s0277-5387(96)00523-2

  日期：1997.4

  Abstract In a one-pot reaction, the three titled manganese chloride complexes were prepared by refluxing Mn2(CO)10 with (PP) in 2-chloroethanol for two hours. The new compounds were characterized by IR, 1H NMR, mass spectra and microanalyses. The X-ray crystal structure of fac-Mn(CO)3(depe)Cl is also reported.

  摘要在一锅法反应中，将Mn2（CO）10与（PP）在2-氯乙醇中回流2小时，制得了三种标题的氯化锰配合物。通过IR，1H NMR，质谱和显微分析对这些新化合物进行了表征。还报道了fac-Mn（CO）3（depe）Cl的X射线晶体结构。
• Reaction of electrophiles with manganese(I) and rhenium(I) alkoxide complexes: reversible absorption of atmospheric carbon dioxide
  作者：Santosh K. Mandal、Douglas M. Ho、Milton Orchin

  DOI：10.1021/om00029a032

  日期：1993.5

  The transition metal alkoxides fac-(CO)3(P-P)MOR [where M is Mn or Re, P-P is either 1,2-bis(diphenylphosphino)ethane (dppe) or 1,3-bis(diphenylphosphino)propane (dppp), and R is either CH3, C2H5, or CF3CH2] react readily at room temperature with CO2, CS2, and PhNCO by insertion of these electrophiles into the metal-oxygen bond. The reactions with C02 leading to the corresponding carbonato complexes fac-(CO)3(P-P)MOC(O)OR are of special interest; benzene solutions of the alkoxides can even absorb CO2 from the atmosphere. All the carbonato complexes release C02 When argon is bubbled through solutions of them, regenerating the alkoxides. These equilibrium reactions make it possible to exchange the C02 of the carbonato complexes by treatment of them with CS2 or PhNCO. Only the C02 reaction is reversible under mild conditions. When a solution of fac-(CO)3(dppe)MnOC(O)OCH3 is treated with CH3NH2 followed by CO2 the metallourethane complex (CO)3(dppe)MnOC(O)NHCH3 is formed. The X-ray crystal structure of fac-(CO)3(dppe)MnOC(O)OCH3 is presented.
• Structural Characterization of Several (CO)₃(dppp)MnX Derivatives, dppp = 1,3-Bis(diphenylphosphino)propane and X = H, OTs, OC₂H₅, Cl, Br, or N₃. An Assessment of Their Efficacy for Catalyzing the Coupling of Carbon Dioxide and Epoxides
  作者：Donald J. Darensbourg、Poulomi Ganguly、Damon R. Billodeaux

  DOI：10.1021/om049352v

  日期：2004.12.1

  The X-ray structures of a series of (CO)(3)(dppp)MnX complexes, X = H, OTs, OEt, Cl, Br, and N-3, and dppp = 1,3-bis(diphenylphosphino)propane, prepared by literature methods are reported. Several of these derivatives have been examined for their ability to serve as catalysts for the coupling of cyclohexene oxide and carbon dioxide. Although, these organometallic complexes do catalyze the formation of polycarbonate, their activity is not competitive with other very effective catalysts for this coupling reaction. Nevertheless, findings from these studies contribute significantly to our understanding of this important process. The complex containing the alkoxide ligand is the most active, yet it possesses a TON (mol epoxide consumed/mol Mn) of only 50 for a 24 h reaction. In this instance the (CO)(3)(dppp)MnOEt complex exists as the carbonate species, (CO)(3)(dppp)MnOC(O)OEt, because of rapid CO2 insertion into the Mn-OEt bond. The order of epoxide ring-opening by the X group (initiator) was found to be -OC(O)OR > Cl greater than or equal to N-3 > Br. Furthermore, since these complexes are substitutionally inert, this process is best defined as occurring via an associative interchange process and is rate-limiting.