[(η4-2,5-Ph2H2C4P(O)H)manganesetricarbonyl][K(18-crown-6] | 1202544-07-7

• 英文名称: [(η4-2,5-Ph2H2C4P(O)H)manganesetricarbonyl][K(18-crown-6]
• CAS: 1202544-07-7
• 化学式: C₁₂H₂₄KO₆*C₁₉H₁₃MnO₄P
• 分子量: 694.639
• InChiKey: HOPQFONIBSUTNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  18-冠醚-6 、 η5-2,5-diphenylphosphacymantrene 、 potassium hydroxide 以 二氯甲烷 为溶剂， 生成 [(η4-2,5-Ph2H2C4P(O)H)manganesetricarbonyl][K(18-crown-6]
  参考文献：
  名称：

  The reaction of 2,5-diphenylphosphacymantrene with solid KOH in the presence of crown ethers: Synthesis of the anionic η4-phosphoryl manganese complexes

  摘要：

  2,5-Diphenylphosphacymantrene (1) reacts with solid KOH in the presence of crown ethers in C6H6 or CH2Cl2 at room temperature adding OH nucleophile to the phosphorus atom to afford anionic complexes [(CO)(3)Mn-eta(4)-2,5-Ph2H2C4P(=O)H] [K-Crown](+), where Crown = 18-crown-6 (2) or dicyclohexyl-18-crown-6 (3). Complexes 2 and 3 are characterized by H-1, P-31, C-13 NMR and IR-spectra. The structure of 2 is established by X-ray crystal structure data. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.09.013