[H2NEt2][(CO)3Mn-η4-2,5Ph2C4H2P(=O)H] | 1260018-03-8

• 英文名称: [H2NEt2][(CO)3Mn-η4-2,5Ph2C4H2P(=O)H]
• 英文别名: [(η4-C4H2Ph2P(O)H)Mn(CO)3][NH2Et2]
• CAS: 1260018-03-8
• 化学式: C₄H₁₁N*C₁₉H₁₃MnO₄P*H
• 分子量: 465.368
• InChiKey: VZUBCTATKOAAJH-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  η5-2,5-diphenylphosphacymantrene 、 水 、 二乙胺 以 二氯甲烷 为溶剂， 以60%的产率得到[H2NEt2][(CO)3Mn-η4-2,5Ph2C4H2P(=O)H]
  参考文献：
  名称：

  2,5-二苯基磷酰苯胺与二乙胺在水存在下的反应

  摘要：

  DOI：

  10.1007/s11172-010-0109-0

文献信息

• Change of the coordination type for the phospholyl ligand under nucleophilic attack of H2O on phosphorus atom in 2,5-diphenylphosphacymantrene promoted by aliphatic amines
  作者：Allan G. Ginzburg、Vasily V. Bashilov、Fedor M. Dolgushin、Alexander F. Smol’yakov、Pavel V. Petrovskii、Viatcheslav I. Sokolov

  DOI：10.1016/j.ica.2011.01.094

  日期：2011.5

  eta(5)-2,5-Diphenylphosphacymantrene (1) in benzene or CH2Cl2 solution does not react with amines. However, with amines NHEt2, NEt3, NEt(i-Pr)(2) in excess and in the presence of small amounts of water 1 reacts to form anionic complexes [(CO)(3)Mn(eta(4)-Ph2H2C4P(=O)H] A(+), where cation A = H2NEt2+ (2a), HNEt3+ (2b), HN(Et)(Pr-i)(2)(+) (2c). Probably, first an unstable intermediate with P-OH bond is formed as a result of the attack by the activated H2O molecule at the P atom. Afterwards, the rapid rearrangement occurs with migration of H from O to P which leads to the ligand 2,5-diphenyl-1-H-phosphol-1-oxide, Ph2H2C4P(=O)H. Salts 2a-c have been characterized by H-1, P-31, C-13 NMR- and IR-spectra and the structures of 2a and 2c established by single crystal X-ray diffraction analyses. The phosphoryl ligand in anions 2a and 2c has the "envelope" conformation and is eta(4)-coordinated with Mn(CO)(3). The phosphorus atom is not involved in the coordination with Mn because the Mn-P distances (2.7670(4) and 2.7732(8) angstrom) are greater than the sum of covalent radii of P and Mn. (C) 2011 Elsevier B.V. All rights reserved.