[Ru(η6-triphenylene)(1-5-η5-cyclooctadienyl)]PF6 | 942293-23-4

• 英文名称: [Ru(η6-triphenylene)(1-5-η5-cyclooctadienyl)]PF6
• CAS: 942293-23-4
• 化学式: C₂₆H₂₃Ru*F₆P
• 分子量: 581.503
• InChiKey: QHIJHOWRJSUIGZ-IGIVYXTLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Ru(η6-triphenylene)(1-5-η5-cyclooctadienyl)]PF6 、 苯 以 二氯甲烷-D2 为溶剂， 生成 (η-6-benzene)(η-5-cycloocta-1,5-dienyl)ruthenium hexafluorophosphate
  参考文献：
  名称：

  Synthesis of di-, tri-, tetra- and pentacyclic arene complexes of ruthenium(II):[Ru(η6-polycyclic arene)-(1-5-η5-cyclooctadienyl)]PF6 and their reactions with NaBH4

  摘要：

  The phenanthrene complex of ruthenium(II), [Ru(eta(6)-phenanthrene)(1,5-eta(5)-cyclooctadienyl)]PF6 (2c), is prepared by the reaction of Ru(eta(4)-1,5-COD)(eta(6)-1,3,5-COT) (1) with phenanthrene and HPF6 in 65% yield. Similar treatments with di- tri-, tetra- and pentacyclic arenes give corresponding polycyclic arene complexes, [Ru(eta(6)-polycyclic arene)(1-5-eta(5)-cyclooctadienyl)]PF6 [polycyclic arene = naphthalene (2b), anthracene (2d), triphenylene (2e), pyrene (2f) and perylene (2g)] in 46-90% yields. The molecular structure of the perylene complex 2g is characterized by X-ray crystallography. Reaction of 2c with NaBH4 gives a mixture of the 1,5- and 1,4-COD complexes of ruthenium(0), Ru(eta(6)-phenanthrene)(eta(4)-1,5-COD) (3c) and Ru(eta(6)-phenanthrene)(eta(4)-1,4-COD) (4c) in 76% in 1:8 molar ratio. The arene exchange reactions among cationic complexes [Ru(eta(6)-arene)(1-5-eta(5)-cyclooctadienyl)]PF6 (2) showed the coordination ability of arenes in the following order: benzene similar to triphenylene > phenanthrene > naphthalene > perylene similar to pyrene > anthracene, suggesting the benzo fused rings, particularly those of acenes, decreasing thermal stability of the arene complex. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.02.023
• 作为产物：
  描述：

  9,10-苯并菲 、 [Ru(η6-phenanthrene)(1-5-η5-cyclooctadienyl)]PF6 以 二氯甲烷-D2 为溶剂， 生成 [Ru(η6-triphenylene)(1-5-η5-cyclooctadienyl)]PF6
  参考文献：
  名称：

  Synthesis of di-, tri-, tetra- and pentacyclic arene complexes of ruthenium(II):[Ru(η6-polycyclic arene)-(1-5-η5-cyclooctadienyl)]PF6 and their reactions with NaBH4

  摘要：

  The phenanthrene complex of ruthenium(II), [Ru(eta(6)-phenanthrene)(1,5-eta(5)-cyclooctadienyl)]PF6 (2c), is prepared by the reaction of Ru(eta(4)-1,5-COD)(eta(6)-1,3,5-COT) (1) with phenanthrene and HPF6 in 65% yield. Similar treatments with di- tri-, tetra- and pentacyclic arenes give corresponding polycyclic arene complexes, [Ru(eta(6)-polycyclic arene)(1-5-eta(5)-cyclooctadienyl)]PF6 [polycyclic arene = naphthalene (2b), anthracene (2d), triphenylene (2e), pyrene (2f) and perylene (2g)] in 46-90% yields. The molecular structure of the perylene complex 2g is characterized by X-ray crystallography. Reaction of 2c with NaBH4 gives a mixture of the 1,5- and 1,4-COD complexes of ruthenium(0), Ru(eta(6)-phenanthrene)(eta(4)-1,5-COD) (3c) and Ru(eta(6)-phenanthrene)(eta(4)-1,4-COD) (4c) in 76% in 1:8 molar ratio. The arene exchange reactions among cationic complexes [Ru(eta(6)-arene)(1-5-eta(5)-cyclooctadienyl)]PF6 (2) showed the coordination ability of arenes in the following order: benzene similar to triphenylene > phenanthrene > naphthalene > perylene similar to pyrene > anthracene, suggesting the benzo fused rings, particularly those of acenes, decreasing thermal stability of the arene complex. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.02.023