HC[C(Me)N(2,6-iPr2C6H3)]2Al(SSiMe2)2O | 863482-05-7

• 英文名称: HC[C(Me)N(2,6-iPr2C6H3)]2Al(SSiMe2)2O
• CAS: 863482-05-7
• 化学式: C₃₃H₅₃AlN₂OS₂Si₂
• 分子量: 641.081
• InChiKey: YCAKVDPKOYUQCT-VCGBEGQOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)2 以 四氢呋喃 为溶剂， 生成 HC[C(Me)N(2,6-iPr2C6H3)]2Al(SSiMe2)2O
  参考文献：
  名称：

  Unusual Anions [LAl(SH)(S)]^- and [LAl(S)₂]^2- Stabilized by Weakly Coordinating Imidazolium Cations. Synthesis of LAl(SSiMe₂)₂O (L = HC[C(Me)N(Ar)]₂, Ar = 2,6-iPr₂C₆H₃)

  摘要：

  Deprotonation of an Al-SH moiety has been achieved easily by using N-heterocyclic carbene as the base. Monomeric mono- and bis-imidazolium salts [CtH+][LAI(SH)(S)](-) ([CtH+] = N,N'-bis-tert-butylimidazolium), [CmH+][LAI(SH)(S)](-), and [CmH+](2)[LAI(S)(2)](2) ([CmH+] = N,N'-bismesitylimidazolium), containing unusual anions [LAI(SH)(S)](-) and [LAI(S)(2)](2-), have been synthesized in nearly quantitative yields, Furthermore, [CmH+](2)[LAI(S)(2)](2) has been successfully used for the preparation of LAI(SSiMe2)(2)O containing the [O(Me2SiS)(2)](2-) ligand.

  DOI：

  10.1021/ic050693q