Re4(μ3-Te)4(TeCl2)4Cl8 | 186195-58-4

• 英文名称: Re4(μ3-Te)4(TeCl2)4Cl8
• CAS: 186195-58-4
• 化学式: Cl₁₆Re₄Te₈
• 分子量: 2332.88
• InChiKey: GVHFJLODXUPELG-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium cyanide 、 Re4(μ3-Te)4(TeCl2)4Cl8 以 水 为溶剂， 生成
  参考文献：
  名称：

  基于簇阴离子 [Re4Te4(CN)12]4− 和 Zn2+ 阳离子的配位化合物

  摘要：

  三种新型配位化合物 [{Zn(H2O)2} {Zn(H2O)4} Re4Te4(CN)12] (1), [Zn(en)2(NH3)2][{Zn(en)(NH3)2 } Re4Te4(CN)12]·H2O(2)和[{Zn2(dien)3}Re4Te4(CN)12]··6H2O(3)(dien是二亚乙基三胺)是由四面体簇的水溶液反应制备的在氨、乙二胺和二亚乙基三胺存在下，铼碲氰化物配合物 K4[Re4Te4(CN)12]·5H2O 与二氯化锌。配合物 1 具有二维结构，具有两种类型的 Zn 原子；配合物2与聚合物链阴离子是离子的；复合物3具有分子结构。通过单晶X射线衍射分析确定了配合物1-3的结构。

  DOI：

  10.1007/s11172-006-0324-x
• 作为产物：
  描述：

  碲化氢 、 rhenium(V) chloride 以 not given 为溶剂， 生成 Re4(μ3-Te)4(TeCl2)4Cl8
  参考文献：
  名称：

  New cyano-bridged complexes based on tetrahedral rhenium chalcocyanide clusters, Cu2+ cations, and polydentate amines

  摘要：

  三种新的氰基桥化合物，即[{Cu(en)}{Cu(NH3)(en)}Re4Se4(CN)12]·{5H2O (1)、[{Cu(dien)}2Re4Te4(CN)通过四面体硫氰化铼簇配合物 K4[Re4Q4(CN)12] 的反应合成了 12]·9H2O (2) 和 [{Cu(trien)}2Re4Se4(CN)12]··5H2O (3) ( (Q = Se 或 Te) 与铜 (II) 阳离子在含有乙二胺 (en)、二亚乙基三胺 (dien) 或三亚乙基四胺 (trien) 的水溶液中分别具有梯状管状聚合结构，其中两个。无限链通过Re-CN-Cu桥相互连接，化合物2具有聚合链结构，化合物3具有分子结构。所有配合物的结构均通过X射线衍射分析确定。

  DOI：

  10.1007/s11172-005-0085-y

文献信息

• Tetranuclear rhenium chalcochloride cluster complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Se and Te): Synthesis and structures
  作者：Yu. V. Mironov、O. A. Efremova、S. S. Yarovoi、V. E. Fedorov

  DOI：10.1134/s1070328409050017

  日期：2009.5

  tetranuclear cluster rhenium complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Te (I) and Se (II)) with the Cl atoms as terminal ligands were obtained and structurally characterized. The structures of complexes I and II were determined by X-ray diffraction analysis. Their isostructural crystals are monoclinic; space group C2, Z = 6; a = 26.403(8) Å, b = 16.495(5) Å, c = 11.744(3) Å, β = 91.25(2)°, V = 5113(2) Å3 (I); a

  得到了以Cl原子为末端配体的四核簇rh配合物Cs 3 H [Re 4 Q 4 Cl 12 ]·3.33H 2 O（Q = Te（I）和Se（II）），并进行了结构表征。配合物I和II的结构通过X射线衍射分析确定。它们的同构晶体是单斜晶的。空间组C 2，Z = 6；一个= 26.403（8）埃，b = 16.495（5），C ^ = 11.744（3），β= 91.25（2）°，V = 5113（2）埃3（我）; 一个= 26.573（3）埃，b = 16.461（3）埃，c ^ = 11.726（2）埃，β= 91.381（4）°，V = 5127.6（14）一种3（II）。
• Tetrahedral chalcogeno thiocyanate cluster complexes [Re4Q4(SCN)12]4− (Q=S, Se, Te): synthesis and crystal structures
  作者：Yuri V. Mironov

  DOI：10.1016/s0277-5387(99)00382-4

  日期：2000.2

  The [Re(4)Q(4)(SCN)(12)](4-) (Q = S, Se, Te) anions were obtained by the reactions of neutral molecular clusters Re44QCl8(TeCl2)(4), Q = S, Se, Te, with melting KSCN. Crystal structures were determined for the isostructural compounds (Ph4P)(4)Re-44S(SCN)(12) (1), (Ph4P)(4)Re4Se4(SCN)(12) (2) and (Ph4As)(4)Re(4)T4(e)(SCN)(12) (3). Each contains an Re(4)Q(4) cubane-like cluster core with Re-Re distances in the ranges 2.762(3)-2.768(2) Angstrom (1), 2.799(2)-2.803(2) Angstrom (2) and 2.864(2)-2.877(2) Angstrom (3). The faces of the Re, units are symmetrically capped by triply bridging chalcogenide ligands Q(2-) (Q = S, Se, Te). (C) 2000 Elsevier Science Ltd All rights reserved.
• Mironov, Yuri V.; Albrecht-Schmitt, Thomas E.; Ibers, James A., Inorganic Chemistry, 1997, vol. 36, p. 944 - 946
  作者：Mironov, Yuri V.、Albrecht-Schmitt, Thomas E.、Ibers, James A.

  DOI：——

  日期：——
• Isomerism in tetrahedral rhenium cluster complexes [Re4Q4(PMe2Ph)4X8]·nCH2Cl2 (Q=Se, X=Br; Q=Te, X=Cl, Br)
  作者：Olga A. Efremova、Yuri V. Mironov、Konstantin A. Brylev、Vladimir E. Fedorov、Hans-Jürgen Pietzsch、Holger Stephan

  DOI：10.1016/j.poly.2009.07.003

  日期：2009.9

  Three new tetrahedral rhenium cluster compounds [Re4Se4(PMe2Ph)(4)Br-8]center dot 1.5CH(2)Cl(2) (1), [Re4Te4(PMe2Ph)(4)Br-8]center dot CH2Cl2 (2), and [Re4Te4(PMe2Ph)(4)Cl-8]center dot CH2Cl2 (3) have been synthesized by the reaction of the corresponding precursor chalcohalide complexes [Re(4)Q(4)(TeX2)(4)X-8] (X = Br, Q = Se (for 1), Te (for 2); X=Cl, Q=Te (for 3)) with dimethylphenylphosphine in CH2Cl2. All compounds have been characterized by X-ray single-crystal diffraction and elemental analyses, IR and P-31 NMR spectroscopy. P-31 NMR spectroscopy indicates the formation of isomers in solution, confirmed by single-crystal X-ray analysis. (C) 2009 Elsevier Ltd. All rights reserved.
• ——
  作者：Yu. V. Mironov、O. A. Efremova、V. E. Fedorov、O. Oeckler、A. Simon、C. Vicent、R. Llusar

  DOI：10.1023/a:1026079932176

  日期：——

  The reactions of aqueous solutions of the tetranuclear chalcocyanide cluster anions [Re(4)Q(4)(CN)(12)](4-), where Q = S, Se, or Te, with an ammonia solution of copper(II) chloride at room temperature afforded a series of polymeric cyano-bridged compounds [Cu(NH3)(3)}(2)Re(4)Q(4)(CN)(12)}].nH(2)O (Q = S (1), Se (2)) and [Cu(NH3)(3)}(1.7)Cu(NH3)(4)}(0.3)Re4Te4(CN)(12)] (3) having chain structures. The structures of the compounds were established by X-ray diffraction analysis. Compounds I and 2 are isostructural and have ordered structures. In structurally similar compound 3, the copper atoms are disordered over two positions in such a way that the structure contains the bridging Cu(NH3)(3)} fragments along with the terminal Cu(NH3)(4)} fragments.