[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl | 477178-18-0

• 英文名称: [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl
• CAS: 477178-18-0
• 化学式: C₂₇H₂₂ClNO₂Ru
• 分子量: 529.0
• InChiKey: FKEJBNPPTJXBSS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl 在 sodium methoxide 作用下， 以 not given 为溶剂， 生成 [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2H
  参考文献：
  名称：

  Protonated Aminocyclopentadienyl Ruthenium Hydride Reduction of Benzaldehyde and the Conversion of the Resulting Ruthenium Triflate to a Ruthenium Hydride with H₂ and Base

  摘要：

  Reaction of N-phenyl-2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dienimine (6) with Ru3CO12 formed two isomers of {[2,5-Me-2-3,4-Ph-2(eta(5) -C4CNHPh)]Ru(CO)(mu-CO)}(2) (8-trans and 8-cis). Photolysis of 8 under a H-2 atmosphere led to the formation of the aminocyclopentadienyl ruthenium hydride [2,5-Me-2-3,4-Ph-2(eta(5)-C4CNHPh)]Ru(CO)(2)H (9-H). 9-H reduced benzaldehyde slowly at 75 degreesC to give benzyl alcohol and 8. Protonation of 9-H with triflic acid produced {[2,5-Me-2-3,4-Ph-2(eta(5)-C4CNH2Ph)]Ru(CO)(2)H}OTf (11-H), which reacted rapidly with benzaldehyde at -80 degreesC to give benzyl alcohol and [2,5-Me-2-3,4-Ph-2(eta5-C4CNHPh)]Ru(CO)(2)OTf(9-OTf). Reaction of 9-OTf with H2 and base led to the re-formation of 9-H. These reactions provide the transformations required for a catalytic cycle for hydrogenation of aldehydes.

  DOI：

  10.1021/om020507d
• 作为产物：
  描述：

  二氯甲烷-D2 、 ([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2 以 二氯甲烷-D2 为溶剂， 生成 [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl
  参考文献：
  名称：

  Protonated Aminocyclopentadienyl Ruthenium Hydride Reduction of Benzaldehyde and the Conversion of the Resulting Ruthenium Triflate to a Ruthenium Hydride with H₂ and Base

  摘要：

  Reaction of N-phenyl-2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dienimine (6) with Ru3CO12 formed two isomers of {[2,5-Me-2-3,4-Ph-2(eta(5) -C4CNHPh)]Ru(CO)(mu-CO)}(2) (8-trans and 8-cis). Photolysis of 8 under a H-2 atmosphere led to the formation of the aminocyclopentadienyl ruthenium hydride [2,5-Me-2-3,4-Ph-2(eta(5)-C4CNHPh)]Ru(CO)(2)H (9-H). 9-H reduced benzaldehyde slowly at 75 degreesC to give benzyl alcohol and 8. Protonation of 9-H with triflic acid produced {[2,5-Me-2-3,4-Ph-2(eta(5)-C4CNH2Ph)]Ru(CO)(2)H}OTf (11-H), which reacted rapidly with benzaldehyde at -80 degreesC to give benzyl alcohol and [2,5-Me-2-3,4-Ph-2(eta5-C4CNHPh)]Ru(CO)(2)OTf(9-OTf). Reaction of 9-OTf with H2 and base led to the re-formation of 9-H. These reactions provide the transformations required for a catalytic cycle for hydrogenation of aldehydes.

  DOI：

  10.1021/om020507d

文献信息

• Redox reaction between benzyl azides and aryl azides: concerted synthesis of aryl nitriles and anilines
  作者：Yongjin Kim、Young Ho Rhee、Jaiwook Park

  DOI：10.1039/c6ob02615j

  日期：——

  unique and novel reaction between benzyl azides and aryl azides is described to synthesize aryl nitriles and anilines concurrently, which is catalyzed with a photoactivated diruthenium complex. N-Unsubstituted imines (N–H imines) are generated first from benzyl azides, followed by the hydrogen transfer reaction between N–H imines and aryl azides. A wide range of aryl nitriles and anilines were synthesized

  描述了苄基叠氮化物和芳基叠氮化物之间独特且新颖的反应，其以光活化的二钌配合物催化同时合成芳基腈和苯胺。N-未取代的亚胺（NH-亚胺）首先由叠氮化物生成，然后是NH-亚胺与芳基叠氮化物之间的氢转移反应。在中性和温和的反应条件下合成了多种芳基腈和苯胺。
• Synthesis and Reactivity of Hydroxycyclopentadienyl and Aminocyclopentadienyl Ruthenium Alcohol Complexes
  作者：Charles P. Casey、Thomas E. Vos、Galina A. Bikzhanova

  DOI：10.1021/om020891e

  日期：2003.3.1

  Cationic aminocyclopentadienyl and hydroxycyclopentadienyl ruthenium alcohol complexes were synthesized from reaction of the corresponding ruthenium chloride with AgBF4 in the presence of an alcohol. Exchange rates of free alcohol with hydroxycyclopentadienyl and aminocyclopentadienyl ruthenium benzyl alcohol complexes were rapid (t(1/2) = 5-10 min) at -47 degreesC.