(η5-C5Me5)Cl2HfSi(SiMe3)3 | 115677-43-5

• 英文名称: (η5-C5Me5)Cl2HfSi(SiMe3)3
• CAS: 115677-43-5
• 化学式: C₁₉H₄₂Cl₂HfSi₄
• 分子量: 632.28
• InChiKey: XATOLQHPCOMYBD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (η5-C5Me5)Cl2HfSi(SiMe3)3 在 pyridine 作用下， 以 正戊烷 为溶剂， 以80%的产率得到(η5-C5Me5)Cl2HfSi(SiMe3)3(py)
  参考文献：
  名称：

  Arnold, John; Roddick, Dean M.; Tilley, T. Don, Inorganic Chemistry, 1988, vol. 27, # 20, p. 3510 - 3514

  摘要：

  DOI：
• 作为产物：
  描述：

  tris(trimethylsilyl)silyllithium*3(tetrahydrofuran) 、 五甲基环戊二烯基三氯化铪(IV) 以 乙醚 为溶剂， 以75%的产率得到(η5-C5Me5)Cl2HfSi(SiMe3)3
  参考文献：
  名称：

  Arnold, John; Roddick, Dean M.; Tilley, T. Don, Inorganic Chemistry, 1988, vol. 27, # 20, p. 3510 - 3514

  摘要：

  DOI：

文献信息

• Arnold, John; Woo, Hee-Gweon; Tilley, T. Don, Organometallics, 1988, vol. 7, # 9, p. 2045 - 2049
  作者：Arnold, John、Woo, Hee-Gweon、Tilley, T. Don、Rheingold, Arnold L.、Geib, Steven J.

  DOI：——

  日期：——
• Hafnium imido complexes containing silyl ligands
  作者：Ivan Castillo、T. Don Tilley

  DOI：10.1016/s0022-328x(01)01386-9

  日期：2002.2

  The hafnium imido dichloride (2,6-i-Pr2C6H3)N=Hf(THF)(2)Cl-2 (1) reacts with two equivalents of Ph3SiLi(THF)(3) to yield the corresponding disilyl complex (2,6-i-Pr2C6H3)N=Hf(THF)(2)(SiPh3)(2) (2) in low yield. Compound 2 was crystallographically characterized. The hafnium monosityl complex (2,6-i-Pr2C6H3)N=Hf(4-t-BuC5H4N)(2)Cl[Si(SiMe3)(3)] (4) was synthesized in a similar manner from (2,6-i-Pr2C6H3)N=Hf(4-t-BuC5H4N)(2)Cl-2 (3) and one equivalent of (Me3Si)(3)SiK in good yield. The Cp*-containing hafnium imido complex Cp*HfCl[mu-N(2,6-i-Pr2C6H3)]}(2) (5) was prepared by thermolysis of Cp*Hf[Si(SiMe3)(3)][NH(2,6-i-Pr2C6H3)]Cl via loss of (Me3Si)(3)SiH. Complex 5 was crystallographically characterized. Attempts to prepared derivatives of 5 with reactive sigma-bonds resulted in the formation of Cp*-cyclometallated species. (C) 2002 Elsevier Science B.V. All rights reserved.
• Arnold, John; Engeler, Mary P.; Elsner, Frederick H., Organometallics, 1989, vol. 8, # 9, p. 2284 - 2286
  作者：Arnold, John、Engeler, Mary P.、Elsner, Frederick H.、Heyn, Richard H.、Tilley, T. Don

  DOI：——

  日期：——