ferrocenyl nitrile oxide | 405889-30-7

• 英文名称: ferrocenyl nitrile oxide
• CAS: 405889-30-7
• 化学式: C₁₁H₉FeNO
• 分子量: 227.046
• InChiKey: MWWLMFYZUBJMSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ferrocenyl nitrile oxide 、 足球烯 在 triethylamine 作用下， 以 甲苯 为溶剂， 生成 C₆₀(C₅H₄CNO)(C₅H₅)Fe
  参考文献：
  名称：

  STM/STS observation of ferrocene derivative adduct to C60 on HOPG

  摘要：

  The C(60)ONCFn cycloadduct (Fn=ferrocene) was prepared in the reaction between C-60 and ferrocene oxime, the ferrocene derivative was bound to C-60 at the 6-6 bond by a heterocyclic oxygen-nitrogen-carbon ring; the compound was stable in air. The compound dissolved in dichloroethane was deposited on HOPG and observed by UHV STM/STS methods. The molecules of C(60)ONCFn formed several-microns-long straight chains with clearly visible adducted groups pointing to one side of the chain. The STM/STS observations are discussed within the terms of semiempirical quantum chemical molecular modeling. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0368-2048(03)00035-5
• 作为产物：
  描述：

  N-氯代丁二酰亚胺 、 ferrocenecarboxaldoxime 以 二氯甲烷 为溶剂， 生成 ferrocenyl nitrile oxide
  参考文献：
  名称：

  STM/STS observation of ferrocene derivative adduct to C60 on HOPG

  摘要：

  The C(60)ONCFn cycloadduct (Fn=ferrocene) was prepared in the reaction between C-60 and ferrocene oxime, the ferrocene derivative was bound to C-60 at the 6-6 bond by a heterocyclic oxygen-nitrogen-carbon ring; the compound was stable in air. The compound dissolved in dichloroethane was deposited on HOPG and observed by UHV STM/STS methods. The molecules of C(60)ONCFn formed several-microns-long straight chains with clearly visible adducted groups pointing to one side of the chain. The STM/STS observations are discussed within the terms of semiempirical quantum chemical molecular modeling. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0368-2048(03)00035-5