[Pd2(μ-Cl)(CH(CH2CH2PPh2)2)2]BF4 | 1029693-91-1

• 英文名称: [Pd2(μ-Cl)(CH(CH2CH2PPh2)2)2]BF4
• CAS: 1029693-91-1
• 化学式: BF₄*C₅₈H₅₈ClP₄Pd₂
• 分子量: 1214.09
• InChiKey: GACORGXYNWEZAE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  氘代丙酮 、 [Pd2(μ-Cl)(CH(CH2CH2PPh2)2)2]BF4 在 AgBF₄ 作用下， 以 氘代丙酮 为溶剂， 生成 [Pd(acetone-d6)(CH(CH2CH2PPh2)2)](1+)
  参考文献：
  名称：

  Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)

  摘要：

  Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)(2)) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}(2)(mu-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.11.031
• 作为产物：
  描述：

  [PdCl(CH(CH2CH2PPh2)2)] 以 二氯甲烷 、 水 、 丙酮 为溶剂， 生成 [Pd2(μ-Cl)(CH(CH2CH2PPh2)2)2]BF4
  参考文献：
  名称：

  Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)

  摘要：

  Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)(2)) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}(2)(mu-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.11.031