tris(triethyl phosphite)copper(I) chloride | 84040-95-9

• 英文名称: tris(triethyl phosphite)copper(I) chloride
• CAS: 84040-95-9
• 化学式: C₁₈H₄₅ClCuO₉P₃
• 分子量: 597.47
• InChiKey: SDPWKKLGZIVFPN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.97
• 重原子数：
  32.0
• 可旋转键数：
  21.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  83.07
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  tris(triethyl phosphite)copper(I) chloride 以 二氯甲烷 为溶剂， 生成 ((EtO)3P)4CuH3BCOOC2H5
  参考文献：
  名称：

  Bommer, Jerry C.; Morse, Karen W., Inorganic Chemistry, 1983, vol. 22, # 4, p. 592 - 596

  摘要：

  DOI：
• 作为产物：
  描述：

  copper(l) chloride 、 亚磷酸三乙酯 以 氯仿 为溶剂， 以65%的产率得到tris(triethyl phosphite)copper(I) chloride
  参考文献：
  名称：

  Bommer, Jerry C.; Morse, Karen W., Inorganic Chemistry, 1983, vol. 22, # 4, p. 592 - 596

  摘要：

  DOI：

文献信息

• Phosphite copper(i) trifluoroacetates [((RO)3P)mCuO2CCF3] (m = 1, 2, 3): synthesis, solid state structures and their potential use as CVD precursors
  作者：Robert Mothes、Tobias Rüffer、Yingzhong Shen、Alexander Jakob、Bernhard Walfort、Holm Petzold、Stefan E. Schulz、Ramona Ecke、Thomas Gessner、Heinrich Lang

  DOI：10.1039/c0dt00347f

  日期：——

  (TG). These complexes decompose by phosphite elimination, decarboxylation and dealkylation. Hot-wall Chemical Vapour Deposition (CVD) experiments were carried out at 380 °C using 11c as precursor for the deposition of copper onto pieces of TiN-coated oxidized silicon substrates. Copper layers of high purity were obtained with grain sizes between 200–1200 nm.

  金属有机物[（（RO）3 P）m CuO 2 CCF 3 ]（R = CH 3：11a，m = 1; 11b，m = 2; 11c，m =3。R = CH 2 CH 3：12a，m＝ 1；12b，m＝ 2；12c，m＝ 3。R ＝ CH 2 CF 3：13a，m＝ 1；13b，m＝ 2；13c，m = 3）可以通过[（（RO）3 P）m氯化铜]（R = CH 3：5a，m = 1; 5b，m = 2; 5c，m =3。R = CH 2 CH 3：6a，m = 1; 6b，m = 2; 6c，m = 3） [KO 2 CCF 3 ]（7）或[铜2 O]（8）与HO 2 CCF 3（9）和P（或）3（2，R ＝ CH 3；3，R ＝ CH 2 CH 3；4，R ＝ CH 2 CF 3）。31 P 1 H}已在25和-80°C下研究了NMR光谱[[（（CH 3 O）3 P）m CuO 2 CCF
• Copper(I) formate complexes
  申请人：Wittenbecher Lars

  公开号：US20070197810A1

  公开（公告）日：2007-08-23

  Copper(I) formate complexes of the formula L n Cu(HCOO).x HCOOH, where x is from 0 to 10, n is 1, 2, 3 or 4 and the n ligands L, independently of one another, are each one of the following ligands: a phosphane of the formula R 1 R 2 R 3 P; a phosphite of the formula (R 1 O)(R 2 O)(R 3 O)P; an isocyanide of the formula R 1 —NC; an alkene of the formula R 1 R 2 C═CR 3 R 4 ; or an alkyne of the formula R 1 C≡CR 2 ; where R 1 , R 2 , R 3 and R 4 , independently of one another, are hydrogen, a linear or branched, optionally partly or completely fluorinated alkyl, aminoalkyl, alkoxyalkyl, hydroxyalkyl, phosphinoalkyl or aryl radical of one to 20 carbon atoms; with the exception of triphenylphosphinocopper(I) formate and 1,1,1-tris(diphenyl-phosphinomethyl)ethanecopper(I) formate; are decomposed for depositing metallic copper.

  铜（I）甲酸盐配合物的化学式为LnCu（HCOO）。x HCOOH，其中x取值范围为0至10，n为1、2、3或4，而n配体L独立地可以是以下任一种配体：磷化物的化学式为R1R2R3P；亚磷酸酯的化学式为（R1O）（R2O）（R3O）P；异氰化物的化学式为R1—NC；烯烃的化学式为R1R2C═CR3R4；或炔烃的化学式为R1C≡CR2；其中R1、R2、R3和R4独立地可以是氢、直链或支链的、部分或完全氟化的烷基、氨基烷基、烷氧基烷基、羟基烷基、膦烷基或芳基，碳原子数为1至20；除了三苯基膦铜（I）甲酸盐和1,1,1-三（二苯基膦甲基）乙烷铜（I）甲酸盐之外，这些配合物可分解以沉积金属铜。