bis(cyclopentadienyliron dicarbonyl) disulfane | 80711-20-2

• 英文名称: bis(cyclopentadienyliron dicarbonyl) disulfane
• 英文别名: (μ-S2)[CpFe(CO)2]2；(μS)2[CpFe(CO)2]2
• CAS: 80711-20-2
• 化学式: C₁₄H₁₀Fe₂O₄S₂
• 分子量: 418.057
• InChiKey: GCUIACQBQGWUPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis(cyclopentadienyliron dicarbonyl) disulfane 在 三苯基膦 作用下， 以 氘代丙酮 为溶剂， 生成 bis(cyclopentadienyliron dicarbonyl) monosulfane
  参考文献：
  名称：

  El-Hinnawi, Mahmoud A.; Aruffo, Alejandro A.; Santarsiero, Bernard D., Inorganic Chemistry, 1983, vol. 22, # 11, p. 1585 - 1590

  摘要：

  DOI：
• 作为产物：
  描述：

  dicarbonylcyclopentadienylbromoiron(II) 、 lithium disulfide 以 四氢呋喃 为溶剂， 生成 (μ-S3)((η5-C5H5)Fe(CO)2)2 、 bis(cyclopentadienyliron dicarbonyl) disulfane
  参考文献：
  名称：

  El-Hinnawi, Mahmoud A.; Aruffo, Alejandro A.; Santarsiero, Bernard D., Inorganic Chemistry, 1983, vol. 22, # 11, p. 1585 - 1590

  摘要：

  DOI：

文献信息

• Synthesis and structures of CpFe(CO)2(κE-ECS2Ph) and [CpFe(CO)(κ2S,E-ECS2Ph)] (E=S, Se)
  作者：Mohammad El-khateeb、Alexander Roller

  DOI：10.1016/j.poly.2007.04.010

  日期：2007.8

  The iron trithiocarbonato complex CpFe(CO)(2)(kappa S-SCS2Ph) (1a) and its selenodithiocarbonato, analogue CpFe(CO)(2)(kappa Se-SeCS2Ph) (1b) were generated by room temperature reactions of (mu-E-x)[CpFe(CO)(2)](2) (E = S; x = 2, 3. E = Se; x = 1) with PhSC(S)Cl. These compounds can be converted into the complexes CpFe(Co)(kappa S-2,E-ECS2Ph) [E = S (2a), Se (2b)], in which the trithiocarbonato or the selenodithiocarbonato ligand is bonded to the iron in a chelate form, under photolytic conditions. The composition and structure of all products have been verified by elemental analyses, IR and H-1 NMR spectroscopies. The crystal structures for compounds la, 1b, and 2b show a three-legged piano-stool configuration at Fe in each complex. The spectroscopic and structural data in this work are commensurate with the electronic factor of the S- and Se-donor ligands. (c) 2007 Elsevier Ltd. All rights reserved.
• O-Alkylthio- and O-alkylselenooxalate iron complexes: Structures of CpFe(CO)2ECOCO2Me and [CpFe(CO)2ECO]2
  作者：Mohammad El-khateeb、Helmar Görls、Wolfgang Weigand

  DOI：10.1016/j.ica.2006.08.002

  日期：2007.2

  When the iron sulfide complexes (mu-S-x)[CpFe(CO)(2)](2) (x = 2,3) are treated with O-alkyl oxalyl chlorides ROCOCOCl the complexes CpFe(CO)(2)SCOCO2R (1) [R = Me (a), Et (b)] are obtained. Similarly, the complexes CpFe(CO)(2)SeCOCO2R (2) are obtained from the analogous iron selenide (g-Se)[CpFe(CO)(2)](2) reaction with the same reagents. Treatment of the iron selenide with half equivalent of oxalyl chloride produces the dimeric complex [CpFe(CO)(2)SeCO](2) (3). The new complexes, 1, 2 and 3, have been characterized by elemental analyses, IR and H-1 NMR spectroscopy. The solid state structures of 1a, 2a, 3 and [CpFe(CO)(2)SCO](2) (4) were determined by an X-ray crystal structure analysis. (c) 2006 Published by Elsevier B.V.